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The Evidence for Linearly Scaling Ocean Gas Exchange With Sea Ice Needs Strengthening
Centre for Geography and Environmental Science, University of Exeter, Penryn, UK.ORCID iD: 0000-0002-7842-4925
Plymouth Marine Laboratory, Plymouth, UK.ORCID iD: 0000-0002-4108-7048
Environment and Sustainability Institute, University of Exeter, Penryn, UK.
Uppsala University, Disciplinary Domain of Science and Technology, Earth Sciences, Department of Earth Sciences, Air, Water and Landscape Sciences.ORCID iD: 0000-0003-1209-289x
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2026 (English)In: Journal of Geophysical Research - Biogeosciences, ISSN 2169-8953, E-ISSN 2169-8961, Vol. 131, no 7, article id e2025JG009346Article in journal (Refereed) Published
Abstract [en]

Polar oceans are critical components of the oceanic uptake of atmospheric carbon dioxide. Estimates of this uptake across the air-sea interface require parameterizations of gas transfer velocity that account for variable sea ice concentrations. Previous studies, using eddy covariance measurements of gas exchange, have concluded that linear scaling of carbon dioxide gas transfer with sea ice concentration is appropriate. The influence of sea ice concentration data resolution and associated uncertainties in these analyses has not been fully examined. Here we re-assess published in situ air-sea gas exchange data from the Arctic and Southern Oceans using a selection of sea ice concentration data sets. In the Southern Ocean, the linear scaling assumption holds irrespective of spatial resolution. In the Arctic Ocean, deviation from the linear case occurs at ice concentrations as low as 50%. Greater deviations become apparent in both polar oceans when sea ice concentration data uncertainties are considered. In the Southern Ocean, results using satellite data sets remain consistent with linear scaling, while ship-based observations indicate greater suppression of uptake within the marginal ice zone. The Arctic response, after including uncertainties, indicates that gas exchange could be suppressed in regions with ice concentrations of 50% or higher. The contrast between the Arctic and Southern Ocean data sets potentially reflects differences in sea ice variability and environmental conditions during the observation periods, with the Arctic data capturing a transitional regime. Linear scaling may therefore serve as a first-order approximation, but intermediate to high ice concentrations, particularly in the Arctic, require further investigation.

Place, publisher, year, edition, pages
American Geophysical Union (AGU), 2026. Vol. 131, no 7, article id e2025JG009346
National Category
Oceanography, Hydrology and Water Resources
Identifiers
URN: urn:nbn:se:uu:diva-595281DOI: 10.1029/2025jg009346ISI: 001830718600001Scopus ID: 2-s2.0-105045986323OAI: oai:DiVA.org:uu-595281DiVA, id: diva2:2091339
Funder
NERC - the Natural Environment Research Council, NE/L002434/1NERC - the Natural Environment Research Council, NE/N018095/1NERC - the Natural Environment Research Council, NE/P021409/1Knut and Alice Wallenberg Foundation, 2016‐0024Available from: 2026-08-11 Created: 2026-08-11 Last updated: 2026-08-12Bibliographically approved

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Watts, JenniferBell, Thomas G.Prytherch, JohnButterworth, Brian J.Else, BrentMiller, ScottHolding, ThomasShutler, Jamie D.
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