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Thermally activated delayed fluorescence chiral molecules exhibiting photoinduced radical emission
Ningbo Univ Technol, Coll Mat Sci & Chem Engn, Ningbo 315211, Peoples R China..
Wroclaw Univ Sci & Technol, Fac Chem, PL-50370 Wroclaw, Poland..
Fudan Univ, Sch Intelligent Mat & Future Energy Innovat, Shanghai 200433, Peoples R China..
Shanghai Univ, Inst Translat Med, Shanghai, Peoples R China..
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2026 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 62, no 33, p. 8486-8490Article in journal (Refereed) Published
Abstract [en]

Room-temperature stable, photoinduced radical emission is achieved in chiral D-A-D ' thermally activated delayed fluorescence (TADF) molecules doped in poly(methyl methacrylate) (PMMA). Host-guest interactions suppress non-radiative decay, enhancing TADF and enabling reversible radical emission via an anti-Kasha process from higher excited states (D2/D3). This offers new strategies for photoresponsive materials.
Place, publisher, year, edition, pages
Royal Society of Chemistry, 2026. Vol. 62, no 33, p. 8486-8490
National Category
Atom and Molecular Physics and Optics Materials Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-589513DOI: 10.1039/d6cc01726fISI: 001739581500001PubMedID: 41979644Scopus ID: 2-s2.0-105035687641OAI: oai:DiVA.org:uu-589513DiVA, id: diva2:2091345
Funder
National Academic Infrastructure for Supercomputing in Sweden (NAISS), naiss2025-5-140Swedish Research Council, 2022-06725Swedish Research Council, 2024-05286Available from: 2026-08-11 Created: 2026-08-11 Last updated: 2026-08-11Bibliographically approved

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