Multi-user extended reality (XR) is an advanced technology that immerses users simultaneously into the meta-verse, aiming to provide a real-time interaction experience in different scenarios. However, different users' network conditions cause data transmission to be asynchronous. It forces users' behavior in the metaverse to go out of sync, seriously impacting the user experience. This paper presents a framework for human-centred synchronization of networks and metaverse applications, often denoted as Intelligent Realities, using Digital Twin (DT) technologies for the networks (network DTs) as well as for the individual users' XR parts (XR DTs). Our framework uses users' attention as a key input to dynamically allocate network resources and align content, thereby keeping widely distributed users in sync. To motivate this framework, we surveyed recent DT-based XR and network systems and found a significant gap: few studies work on synchronizing systems between network DTs and XR DTs. This highlights the need to explore integrated solutions for networked real-time multi-user interaction in the metaverse.