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On the influence of imperfections on microstructure and properties of recycled Al-Si casting alloys
Högskolan i Jönköping, Tekniska Högskolan, JTH. Forskningsmiljö Material och tillverkning – Gjutning. Högskolan i Jönköping, Tekniska Högskolan, JTH, Material och tillverkning.ORCID-id: 0000-0003-4005-812X
2017 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Abstract [en]

There are great energy savings to be made by recycling aluminium; as little as 5% of the energy needed for primary aluminium production may be required. Striving to produce high quality aluminium castings requires knowledge of microstructural imperfections, which is extra important when casting recycled aluminium that generally contains higher levels of imperfections compared to primary aluminium. Imperfections include amongst others Si, Fe, and Mn as well as oxides. Si is needed for castability, but it may also initiate fracture. There are different types of Fe-rich intermetallics influencing properties of castings, generally in a negative direction. Oxides constitute cracks and they are elusive because they are difficult to quantify.

This thesis aims to increase knowledge about imperfections in recycled aluminium castings originating from alloying elements and the melt. Experiments were performed in advanced laboratory equipment, including X-radiographic imaging during solidification and in-situ tensile testing in a scanning electron microscope. Experiments were also performed at industrial foundry facilities.

The experiments showed that the nucleation temperature of primary α-Fe intermetallics increased with higher Fe, Mn, and Cr contents. Primary α-Fe are strongly suggested to nucleate on oxides and to grow in four basic morphologies. Lower nucleation frequency of α-Fe promoted faster growth and hopper crystals while higher nucleation frequency promoted slower growth rates and massive crystals. Results also showed that a decrease in the size of the eutectic Si and plate-like β-Fe intermetallics improved tensile properties, foremost the elongation to fracture. In β-Fe containing alloys the transversely oriented intermetallics initiated macrocracks that are potential fracture initiation sites. In alloys with primary α-Fe foremost clusters of intermetallics promoted macrocracks. In fatigue testing, a transition from β-Fe to α-Fe shifted the initiation sites from oxides and pores to the α-Fe, resulting in a decrease of fatigue strength. Oxides in Al-Si alloys continue to be elusive; no correlations between efforts to quantify the oxides and tensile properties could be observed.

Abstract [sv]

Genom att återvinna aluminium kan stora energibesparingar göras eftersom återvinning kan förbruka så lite som 5% av den energi som behövs för produktion av primär aluminium. Vid gjutning av högkvalitativa aluminiumprodukter krävs förståelse för defekter i mikrostrukturen och denna kunskap är extra viktig vid användning av återvunnen aluminium, som i regel innehåller mer defekter än primär aluminium. Defekterna består bland annat av Si, Fe och Mn samt oxider. Si behövs för gjutbarhet men kan också initiera brott. Järnrika intermetaller kan ha olika morfologier som generellt påverkar gjutna komponenter negativt. Oxider, som kan utgöra sprickor, är gäckande då de är svåra att kvantifiera.

Denna avhandlings syfte är att öka kunskapen om defekter i gjutna komponenter av återvunnen aluminium. Experiment utfördes med avancerad laborationsutrustning så som röntgenfotografering av prover under stelning och dragprovning i svepelektronmikroskop. Experiment utfördes också i industrimiljö.

Experimenten visade att kärnbildningstemperaturen steg för primära α-Fe intermetaller med ökade andelar av Fe, Mn och Cr. Resultaten tyder starkt på att primär α-Fe kärnbildas på oxider och att de växer i fyra olika morfologier. Lägre kärnbildningstäthet av α-Fe främjade snabbare tillväxt av kristaller med håligheter men högre kärnbildningstäthet främjade långsammare tillväxt av massiva kristaller. Resultaten visade också att minskad storlek av eutektiskt Si och β-Fe intermetaller ledde till förbättring av dragprovsresultaten, främst brottförlängningen. I legeringar med β-Fe ledde transversellt orienterade intermetaller till makrosprickor vilka kan initiera brott. I legeringar med primär α-Fe var det främst kluster av intermetaller som orsakade makrosprickor. I utmattningsprovning orsakade modifiering av β-Fe till α-Fe förflyttning av sprickinitieringen från oxider och porer till α-Fe, vilket resulterade i en reducerad utmattningshållfasthet. Oxiderna i Al-Si-legeringar fortsätter att gäcka; ingen korrelation mellan försök att kvantifiera oxiderna och draghållfasthet kunde påvisas.

sted, utgiver, år, opplag, sider
Jönköping: Jönköping University, School of Engineering , 2017. , s. 67
Serie
JTH Dissertation Series ; 28
Emneord [en]
Imperfections, Recycled Al-Si alloys, Fe-rich intermetallics, Melt quality, Fractography
Emneord [sv]
Defekter, Återvunna Al-Si legeringar, Fe-rika intermetaller, Smältakvalité, Fraktografi
HSV kategori
Identifikatorer
URN: urn:nbn:se:hj:diva-36963ISBN: 978-91-87289-29-3 (tryckt)OAI: oai:DiVA.org:hj-36963DiVA, id: diva2:1134894
Disputas
2017-09-15, E1405 (Gjuterisalen), Tekniska Högskolan, Jönköping, 10:00
Opponent
Veileder
Tilgjengelig fra: 2017-08-21 Laget: 2017-08-21 Sist oppdatert: 2025-10-13bibliografisk kontrollert
Delarbeid
1. Assessment of Quality when Delivering Molten Aluminium Alloys Instead of Ingots
Åpne denne publikasjonen i ny fane eller vindu >>Assessment of Quality when Delivering Molten Aluminium Alloys Instead of Ingots
2013 (engelsk)Inngår i: Materials Science Forum, ISSN 0255-5476, E-ISSN 1662-9752, Vol. 765, s. 266-270Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Recycled aluminium alloys manufactured at Stena Aluminium, in Älmhult, Sweden, are delivered in special designed transport containers, called thermoses. Thermoses are best described as an insulating layer protected by a steel cover with a heat loss of about 5 degrees/h. Three thermoses are transported by a truck, giving the possibility for a total capacity of about 24 tonnes delivered aluminium just-in-time to the foundry. By delivering a full load of liquid aluminium, about 2 tonnes of carbon dioxide emissions are saved, compared with delivering ingots. The aim of the paper is to assess the quality benefits, in terms of inclusions sedimentation and mechanical properties, assured by delivering aluminiummelts instead of ingots. The results indicate that materials produced by just-in-time melt delivery have slightly improved quality compared to ingots. The trends are explained in terms of quality, density and bifilm indexes, based on microstructural observations as well as tensile test data analysis.

sted, utgiver, år, opplag, sider
Trans Tech Publications, 2013
HSV kategori
Identifikatorer
urn:nbn:se:hj:diva-20256 (URN)10.4028/www.scientific.net/MSF.765.266 (DOI)2-s2.0-84882945035 (Scopus ID)978-3-03785-766-3 (ISBN)
Konferanse
6th International Light Metals Technology Conference, LMT 2013; Old Windsor; United Kingdom; 24 July 2013 through 26 July 2013
Forskningsfinansiär
Knowledge Foundation
Tilgjengelig fra: 2013-01-17 Laget: 2013-01-17 Sist oppdatert: 2025-10-13bibliografisk kontrollert
2. On the formation of sludge intermetallic particles in secondary aluminum alloys
Åpne denne publikasjonen i ny fane eller vindu >>On the formation of sludge intermetallic particles in secondary aluminum alloys
2015 (engelsk)Inngår i: Metallurgical and Materials Transactions. A, ISSN 1073-5623, E-ISSN 1543-1940, Vol. 46, nr 8, s. 3713-3722Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The primary precipitation of Fe-rich intermetallics in AlSi9Cu3(Fe) type alloys is studied for different Fe, Mn, and Cr contents and cooling rates. Differential scanning calorimetry, thermal analysis, and interrupted solidification with a rapid quenching technique were used in combination in order to assess the nucleation temperature of sludge particles, as well as to follow their evolution. The results revealed that the sludge nucleation temperature and the release of latent heat during sludge formation are functions of Fe, Mn, and Cr levels in the molten alloy (i.e., the sludge factor, SF) and cooling rate. Moreover, it can be concluded that sensitivity to sludge formation is not affected by cooling rate; i.e., a decrease in the SF will reduce sludge nucleation temperature to the same extent for a higher cooling rate as for a lower cooling rate. The sludge formation temperature detected will assist foundries in setting the optimal molten metal temperature for preventing sludge formation in holding furnaces and plunger systems.

sted, utgiver, år, opplag, sider
Springer, 2015
Emneord
aluminium alloys, sludge factor, Fe-rich intermetallics, DSC, thermal analysis
HSV kategori
Identifikatorer
urn:nbn:se:hj:diva-22716 (URN)000356728100039 ()2-s2.0-84932195555 (Scopus ID)
Tilgjengelig fra: 2013-12-13 Laget: 2013-12-13 Sist oppdatert: 2025-10-13bibliografisk kontrollert
3. In-situ study of morphology and growth of primary α-Al(FeMnCr)Si intermetallics in an Al-Si alloy
Åpne denne publikasjonen i ny fane eller vindu >>In-situ study of morphology and growth of primary α-Al(FeMnCr)Si intermetallics in an Al-Si alloy
Vise andre…
2017 (engelsk)Inngår i: Acta Materialia, ISSN 1359-6454, E-ISSN 1873-2453, Vol. 130, s. 1-9Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Morphology and growth of primary α-Al(FeMnCr)Si intermetallics have been studied in-situ during solidification of a commercial secondary aluminum alloy employing X-radiographic imaging combined with deep-etching. The α-Al(FeMnCr)Si intermetallics were found to nucleate primarily on surface oxides, and the continued growth yielded both rhombic dodecahedrons and elongated rod-like morphologies. Both morphologies were observed as hopper and massive types, where the hopper intermetallics had the higher growth rates. The growth rate, which determines the type, appears to be linked to nucleation frequency; higher nucleation frequency promoted massive types and lower nucleation frequency promoted hopper intermetallics. 

sted, utgiver, år, opplag, sider
Elsevier, 2017
Emneord
Aluminum, Casting, Crystal growth, Intermetallics, Primary α-Al(FeMnCr)Si, Aluminum alloys, Hoppers, Morphology, Nucleation, Silicon, Silicon alloys, Deep etching, In-Situ Study, Nucleation frequencies, Rhombic dodecahedron, Rod-like morphology, Secondary aluminum, Surface oxide, X-radiographic imaging
HSV kategori
Identifikatorer
urn:nbn:se:hj:diva-35343 (URN)10.1016/j.actamat.2017.03.026 (DOI)000401388700001 ()2-s2.0-85015790499 (Scopus ID)JTHMaterialIS (Lokal ID)JTHMaterialIS (Arkivnummer)JTHMaterialIS (OAI)
Tilgjengelig fra: 2017-04-10 Laget: 2017-04-10 Sist oppdatert: 2025-10-13bibliografisk kontrollert
4. On the complexity of the relationship between microstructure and tensile properties in cast aluminum
Åpne denne publikasjonen i ny fane eller vindu >>On the complexity of the relationship between microstructure and tensile properties in cast aluminum
2015 (engelsk)Inngår i: International Journal of Modern Physics B, ISSN 0217-9792, Vol. 29, nr 10-11, artikkel-id 1540011Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The relationship between microstructure and mechanical properties in cast aluminium alloys is very complex. This relationship is also strongly affected by the casting process and melt handling. In the current study the mechanical properties were investigated and correlated with microstructural features such as porosity, Fe-rich particles, SDAS, Si-length. Process quality measures such as bifilm index, density index, and sludge factor were also investigated. The aim of the work was to understand the critical interactions between material microstructure and process quality in the development of high performance materials.

Emneord
imperfections, defects, porosity, fe-rich, sdas, silicon, bifilm, density, sludge, mechanical, properties, aluminium, aluminum
HSV kategori
Identifikatorer
urn:nbn:se:hj:diva-24687 (URN)10.1142/S0217979215400111 (DOI)000353523600012 ()2-s2.0-84928555789 (Scopus ID)
Konferanse
Asia Pacific Conference on Materials Processing 2014
Tilgjengelig fra: 2014-12-23 Laget: 2014-09-09 Sist oppdatert: 2025-10-13bibliografisk kontrollert
5. The effects of Fe-particles on the tensile properties of Al-Si-Cu alloys
Åpne denne publikasjonen i ny fane eller vindu >>The effects of Fe-particles on the tensile properties of Al-Si-Cu alloys
2016 (engelsk)Inngår i: Metals, ISSN 2075-4701, Vol. 6, nr 12, artikkel-id 314Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The effect of Fe-rich particles has been a topic for discussion in the aluminum casting industry because of the negative impact they exert on the mechanical properties. However, there are still contradictions on the effects of various morphologies of Fe-particles. In this study, microstructural characterization of tensile tested samples has been performed to reveal how unmodified and modified Fe-rich particles impact on the tensile behavior. Analysis of additions of Fe modifiers such as Mn and Cr, showed higher amounts of primary Fe-rich particles (sludge) with increased porosity and, as result, degraded tensile properties. From the fracture analysis of tensile tested HIPed samples it could be concluded that the mechanical properties were mainly governed by the Fe-rich particles, which were fracturing through cleavage, not by the porosity.

sted, utgiver, år, opplag, sider
MDPI, 2016
Emneord
Fe-rich particles, sludge, tensile properties, fracture, casting, solidification, aluminum, silicon, recycling
HSV kategori
Identifikatorer
urn:nbn:se:hj:diva-26789 (URN)10.3390/met6120314 (DOI)000389600600020 ()2-s2.0-85007193518 (Scopus ID)GOA;;814701 (Lokal ID)GOA;;814701 (Arkivnummer)GOA;;814701 (OAI)
Tilgjengelig fra: 2015-05-28 Laget: 2015-05-28 Sist oppdatert: 2025-10-13bibliografisk kontrollert
6. The effect of Fe-rich intermetallics on crack initiation in cast aluminium: an in-situ tensile study
Åpne denne publikasjonen i ny fane eller vindu >>The effect of Fe-rich intermetallics on crack initiation in cast aluminium: an in-situ tensile study
2019 (engelsk)Inngår i: Materials Science & Engineering: A, ISSN 0921-5093, E-ISSN 1873-4936, Vol. 756, s. 502-507Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

To evaluate the role of Fe-rich intermetallics on crack initiation, two fully modified Al-Si alloys, one containing plate-like β-Fe and the second containing primary α-Fe intermetallics, were investigated by in-situ tensile testing in the scanning electron microscope. In the first alloy, large plate-like β-Fe intermetallics oriented parallel to the test direction were the first to crack at an elongation of about 1.8%. More transversely oriented intermetallics caused crack initiation in the matrix which linked up with the final fracture. In the second alloy, the cracking of α-Fe intermetallics initiated at an elongation of about 0.9%. It is concluded that large α-Fe intermetallics crack first and that clusters of α-Fe are the most potent crack initiation sites.

sted, utgiver, år, opplag, sider
Elsevier, 2019
Emneord
Al-Si alloy, Cast aluminium, Fracture mechanics, Tensile testing in SEM, α-Fe, β-Fe, Aluminum alloys, Crack initiation, Cracks, Fracture testing, Intermetallics, Materials testing apparatus, Metal testing, Scanning electron microscopy, Silicon alloys, Tensile testing
HSV kategori
Identifikatorer
urn:nbn:se:hj:diva-36962 (URN)10.1016/j.msea.2018.07.044 (DOI)000469893400058 ()2-s2.0-85064717473 (Scopus ID)
Tilgjengelig fra: 2017-08-21 Laget: 2017-08-21 Sist oppdatert: 2025-10-13bibliografisk kontrollert
7. Al-Si-Cu alloys for high pressure die casting: Influence of Fe, Mn, and Cr on room temperaturemechanical properties
Åpne denne publikasjonen i ny fane eller vindu >>Al-Si-Cu alloys for high pressure die casting: Influence of Fe, Mn, and Cr on room temperaturemechanical properties
Vise andre…
2016 (engelsk)Inngår i: La Metallurgia Italiana, ISSN 0026-0843, nr 6, s. 77-80Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Al-Si-Cu alloys with high Fe content are widely employed in high pressure die casting (HPDC). Even if Feis usually considered an impurity in secondary aluminum alloys, leading to the formation of harmfulintermetallic compounds, it helps in mitigating or eliminating the problem of die soldering. As a result,secondary Al alloys with Fe content of about 1 wt% are commonly employed for the production of HPDCcastings. Aiming to change the morphology of harmful Fe-bearing phases towards less detrimentalmorphologies, proper alloying elements may be added to the alloys. Mn and Cr (both present in thealuminum scrap), as instance, are reported to prevent from the formation of the acicular β-Al5FeSi phase,leading to the formation of more compact and polygonal intermetallics. Such phases are usually referredto as “sludge” particles. The influence of sludge particles on mechanical properties of Al -Si-Cu castings isstill under investigation. The present work aims at evaluating the effect of impurities (Fe, Mn and Cr)typically present in secondary Al alloys on the microstructure and mechanical properties of the A380 (Al -Si-Cu) alloy. Samples with different Fe, Mn and Cr content were produced and processed through adirectional solidification equipment to obtain specimens with controlled SDAS (~10 μm). Hardness androtating bending fatigue tests were carried out at room temperature. Mechanical properties of the alloyswere then related to the microstructure, analyzed by optical and scanning electron microscopy.

sted, utgiver, år, opplag, sider
Milano: Associazione Italiana di Metallurgia, 2016
Emneord
High pressure die casting, HPDC, Al-Si-Cu alloys, sludge, fatigue, microstructure
HSV kategori
Identifikatorer
urn:nbn:se:hj:diva-31423 (URN)2-s2.0-84993960856 (Scopus ID)JTHMaterialIS (Lokal ID)JTHMaterialIS (Arkivnummer)JTHMaterialIS (OAI)
Konferanse
High Tech Die Casting 2016, Venice, 22-23 June, 2016.
Tilgjengelig fra: 2016-08-22 Laget: 2016-08-22 Sist oppdatert: 2025-10-13

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