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Developing a Renewable Hybrid Resin System: Part I: Characterization of Co-Polymers of Isocyanate with Different Molecular Weights of Phenolic Resins
Mississippi State University, Department of Sustainable Bioproducts, Mississippi.
Central South University of Forestry and Technology, School of Materials Science and Engineering, Changsha, China.
Mississippi State University, Department of Sustainable Bioproducts, Mississippi.
Mississippi State University, Department of Sustainable Bioproducts, Mississippi.
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2016 (English)In: BioResources, ISSN 1930-2126, E-ISSN 1930-2126, Vol. 11, no 2, 5299-5311 p.Article in journal (Refereed) Published
Abstract [en]

Co-polymer systems of methylene diphenyl diisocyanate (MDI) and phenol-formaldehyde (PF) resins with different molecular weights were characterized by infrared spectroscopy (FTIR), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). The FTIR and TGA coupled with differential thermogravimetric (DTG) results showed that higher molecular weight of PF resins not only promoted the reaction of isocyanate and PF co-polymer system, but also resulted in a better thermal property of prepared co-polymers. The XRD results revealed that higher molecular weight led to a higher proportion of ordered or crosslinking structures in the hybrid resin system. The relationship between the thermal resistance, mechanical properties and the molecular weights of phenolic resins needs further study.

Place, publisher, year, edition, pages
2016. Vol. 11, no 2, 5299-5311 p.
National Category
Other Mechanical Engineering
Research subject
Wood Science and Engineering
Identifiers
URN: urn:nbn:se:ltu:diva-15449Local ID: ef56ab14-d38b-4459-879f-864dd26d1dfdOAI: oai:DiVA.org:ltu-15449DiVA: diva2:988423
Note

Validerad; 2016; Nivå 2; 20150827 (aliwan)

Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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fulltext(811 kB)20 downloads
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