Change search
ReferencesLink to record
Permanent link

Direct link
High-flux affinity membranes based on cellulose nanocomposites for removal of heavy metal ions from industrial effluents
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.
University of Maribor, Institute for Engineering Materials and Design, Smetanova ul. 17, SI-2000 Maribor, Slovenia.
Alfa Laval Nakskov A/S, Business Center Membranes, Stavangervej 10, DK-4900, Nakskov, Denmark.
Show others and affiliations
2016 (English)In: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 6, no 25, 20644-20653 p.Article in journal (Refereed) Published
Abstract [en]

Fully biobased affinity membrane processing and its application in the removal of heavy metal ions from mirror industry effluents were successfully demonstrated; indicating the potential use of these membranes in point-of-use or point-of-entry water cleaning products that are cheap, environmentally friendly and efficient. Layered cellulose nanocomposite membranes were fabricated using cellulose microfiber sludge as a support layer and cellulose nanocrystals (CNCSL, CNCBE or PCNCSL) in a gelatin matrix as the functional layer. Scanning electron microscopy (SEM) studies revealed the bi-layered morphology of the membrane and well-individualized nanocelluloses in the functional layer. Bubble point measurements confirmed the membrane pore structure in the microfiltration range (5.0-6.1 μm), which provided very high water permeability (900-4000 L h-1 m-2) at <1.5 bars. A tensile strength of 16 MPa in dry conditions and a wet strength of 0.2 MPa, was considered sufficient for use of these membranes in spiral wound modules. Mirror industry effluent laden with metal ions (Ag+ and Cu2+/Fe3+/Fe2+) when treated with cellulose nanocomposite membranes, showed high ion removal capacity, being 100% for PCNCSL followed by CNCBE than CNCSL. The removal of metal ions was expected to be driven by interactions between negatively charged nanocellulose and the positively charged metal ions.

Place, publisher, year, edition, pages
2016. Vol. 6, no 25, 20644-20653 p.
Research subject
Wood and Bionanocomposites; Chemical Technology
URN: urn:nbn:se:ltu:diva-2929DOI: 10.1039/C5RA27059FLocal ID: 0aa68333-5b84-4a15-b691-1e9f63edee4bOAI: diva2:975783
Validerad; 2016; Nivå 2; 20160217 (magr)Available from: 2016-09-29 Created: 2016-09-29Bibliographically approved

Open Access in DiVA

fulltext(1147 kB)4 downloads
File information
File name FULLTEXT01.pdfFile size 1147 kBChecksum SHA-512
Type fulltextMimetype application/pdf

Other links

Publisher's full text

Search in DiVA

By author/editor
Karim, ZohebMathew, AjiGrahn, Mattias
By organisation
Material ScienceChemical Engineering
In the same journal
RSC Advances

Search outside of DiVA

GoogleGoogle Scholar
Total: 4 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 2 hits
ReferencesLink to record
Permanent link

Direct link