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Para-Selective Halogenation of Nitrosoarenes with Copper(II) Halides
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2015 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 17, no 24, 6210-6213 p.Article in journal (Refereed) Published
Abstract [en]

The para-selective direct bromination and chlorination of nitrosoarenes with copper(II) bromide and chloride is reported. Under mild reaction conditions, a rang of halogenated arylnitroso compounds are obtained in moderate to good yields with high regioselectivity. Additionally, the versatility of the method is demonstrated by the development of a One-pot procedure to obtain the corresponding para-halogenated aniline- and nitrobenzene derivatives.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2015. Vol. 17, no 24, 6210-6213 p.
National Category
Organic Chemistry
URN: urn:nbn:se:su:diva-126203DOI: 10.1021/acs.orglett.5b03198ISI: 000366878300069OAI: diva2:898519
Swedish Research Council
Available from: 2016-01-28 Created: 2016-01-26 Last updated: 2016-02-02Bibliographically approved

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van der Werf, AngelaSelander, Nicklas
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