Validation of MP-AES at the Quantification of Trace Metals in Heavy Matrices with Comparison of Performance to ICP-MS
Independent thesis Basic level (degree of Bachelor), 10 credits / 15 HE creditsStudent thesis
The MP-AES 4200 using microwave plasma and an atomic emission spectroscopy detector provide a new and improved instrument to the analytical field. In this project will the performance of the equipment be evaluated in controlled NaCl-heavy matrices for selected metals (Cu, Zn, Li) and the result from this will be used to optimize a method for specific samples. These samples consist of combustion ashes from the incineration of hazardous waste and are provided by the company SAKAB AB. The sample preparation consisted of several cycles of L/S 10 followed by microwave assisted dissolution with concentrated HNO3, aqua regia or 18.2 MΩ. An extended amount of metals were quantified for these samples (Al, As, Ba, Ca, Cd, Cr, Cu, Fe, K, Li, Mn, Na, Ni, Pb, V, Zn) and most (not Ca, Li, K or Na) were compared with an ICP-MS instrument equipped with a collision cell used for the elements As, Fe and V. A final experiment was made on an L/S 10 of the samples to attempt to separate the metals from the salt with ion exchange, something that would make it possible to recycle this otherwise unused waste.
The detection limits were all in the low μg L-1 except for Cd, Mn and Zn, which were between 2-4 μg L-1. The MP-AES was found to be able to handle matrices up to 5 g L-1 NaCl without a significant loss of response and provided near identical results to the ICP-MS for the elements that could be compared, this did not included the elements not quantified with the ICP-MS or V which was the only element under the limit of detection for the MP-AES. The experiment where an attempt was made to separate the metals from the salt was proven successful after treatment of bark compost and another type of waste ash as cation exchangers.
Place, publisher, year, edition, pages
MP-AES, ICP-MS, high matrices, digestion, microwave plasma, combustion ash, ion exchange
IdentifiersURN: urn:nbn:se:oru:diva-45800OAI: oai:DiVA.org:oru-45800DiVA: diva2:853851
Subject / course