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Synthesis of radiolabelled aryl azides from diazonium salts: experimental and computational results permit the identification of the preferred mechanism
CIC BiomaGUNE, Spain.
University of Basque Country, Spain; Ikerbasque, Spain; Centre Innovac Quim Avanzada ORFEO CINQA, Spain; DIPC, Spain.
CIC BiomaGUNE, Spain.
Linköping University, Department of Medical and Health Sciences. Region Östergötland, Center for Surgery, Orthopaedics and Cancer Treatment, Department of Radiation Physics. Linköping University, Faculty of Medicine and Health Sciences.
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2015 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 51, no 43, 8954-8957 p.Article in journal (Refereed) Published
Abstract [en]

Experimental and computational studies on the formation of aryl azides from the corresponding diazonium salts support a stepwise mechanism via acyclic zwitterionic intermediates. The low energy barriers associated with both transition structures are compatible with very fast and efficient processes, thus making this method suitable for the chemical synthesis of radiolabelled aryl azides.

Place, publisher, year, edition, pages
Royal Society of Chemistry , 2015. Vol. 51, no 43, 8954-8957 p.
National Category
Chemical Sciences
URN: urn:nbn:se:liu:diva-119270DOI: 10.1039/c5cc01913cISI: 000354478700013PubMedID: 25929958OAI: diva2:820597

Funding Agencies|RADIOMI project (EU FP7-PEOPLE-ITN-RADIOMI); Ministerio de Economia y Competitividad (MINECO) of Spain; FEDER [CTQ2013-45415-P]; University of the Basque Country (UPV/EHU) [UFI11/22 QOSYC]; Basque Government (GV/EJ) [IT-324-07]

Available from: 2015-06-12 Created: 2015-06-12 Last updated: 2015-09-09

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