Suppression of the molecular ultra-fast dissociation in bromomethane clusters
2014 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 141, 224305- p.Article in journal (Refereed) Published
We address the influence of clustering on the ultra-fast dissociation of bromomethane. Valence and core photo-electron spectroscopy, partial electron yield absorption, and resonant Auger spectroscopy have been used together with ab initio calculations to investigate the properties of the ultra-fast dissociation. The ratio of ultra-fast dissociation of molecules in clusters as compared to free molecules is determined to be significantly reduced. We propose partial delocalization of the excited electronic state as being responsible for this behavior.
Place, publisher, year, edition, pages
AIP, 2014. Vol. 141, 224305- p.
Research subject Physics with spec. in Atomic, Molecular and Condensed Matter Physics
IdentifiersURN: urn:nbn:se:uu:diva-241035DOI: 10.1063/1.4903455ISI: 000346272800023OAI: oai:DiVA.org:uu-241035DiVA: diva2:777519
FunderSwedish Research Council