Crystallization characteristics and chemical bonding properties of nickel carbide thin film nanocomposites
2014 (English)In: Journal of Physics: Condensed Matter, ISSN 0953-8984, E-ISSN 1361-648X, Vol. 26, no 41, 415501-415512 p.Article in journal (Refereed) Published
The crystal structure and chemical bonding of magnetron-sputtering deposited nickel carbide Ni1−xCx (0.05≤x≤0.62) thin films have been investigated by high-resolution x-ray diffraction, transmission electron microscopy, x-ray photoelectron spectroscopy, Raman spectroscopy, and soft x-ray absorption spectroscopy. By using x-ray as well as electron diffraction, we found carbon-containing hcp-Ni (hcp-NiCy phase), instead of the expected rhombohedral-Ni3C. At low carbon content (4.9 at%), the thin film consists of hcp-NiCy nanocrystallites mixed with a smaller amount of fcc-NiCx. The average grain size is about10–20 nm. With the increase of carbon content to 16.3 at%, the film contains single-phase hcp-NiCy nanocrystallites with expanded lattice parameters. With a further increase of carbon content to 38 at%, and 62 at%, the films transform to x-ray amorphous materials with hcp-NiCy and fcc-NiCx nanodomain structures in an amorphous carbon-rich matrix. Raman spectra of carbon indicate dominant sp2 hybridization, consistent with photoelectron spectra that show a decreasing amount of C–Ni phase with increasing carbon content. The Ni 3d–C 2p hybridization in the hexagonal structure gives rise to the salient double-peak structure in Ni 2p soft x-ray absorption spectra at 16.3 at% that changes with carbon content. We also show thatthe resistivity is not only governed by the amount of carbon, but increases by more than a factor of two when the samples transform from crystalline to amorphous.
Place, publisher, year, edition, pages
Institute of Physics Publishing (IOPP), 2014. Vol. 26, no 41, 415501-415512 p.
Amorphous nanocomposite nickel carbide XRD TEM XAS SAED
IdentifiersURN: urn:nbn:se:liu:diva-110752DOI: 10.1088/0953-8984/26/41/415501ISI: 000343423600004PubMedID: 25237716OAI: oai:DiVA.org:liu-110752DiVA: diva2:748649