Change search
ReferencesLink to record
Permanent link

Direct link
A General Suzuki Cross-Coupling Reaction of Heteroaromatics Catalyzed by Nanopalladium on Amino-Functionalized Siliceous Mesocellular Foam
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
2014 (English)In: Journal of Organic Chemistry, ISSN 0022-3263, E-ISSN 1520-6904, Vol. 79, no 9, 3946-3954 p.Article in journal (Refereed) Published
Abstract [en]

Suzuki-Miyaura cross-coupling reactions of heteroaromatics catalyzed by palladium supported in the cavities of amino-functionalized siliceous mesocellular foam are presented. The nanopalladium catalyst effectively couples not only heteroaryl halides with boronic acids but also heteroaryl halides with boronate esters, potassium trifluoroborates, MIDA boronates, and triolborates, producing a wide range of heterobiaryls in good to excellent yields. Furthermore, the heterogeneous palladium nanocatalyst can easily be removed from the reaction mixture by filtration and recycled several times with minimal loss in activity. This catalyst provides an alternative, environmentally friendly, low-leaching process for the preparation of heterobiaryls.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2014. Vol. 79, no 9, 3946-3954 p.
National Category
Organic Chemistry
URN: urn:nbn:se:su:diva-104396DOI: 10.1021/jo500409rISI: 000335490700024OAI: diva2:724410
Berzelii Centre EXSELENT


Available from: 2014-06-12 Created: 2014-06-10 Last updated: 2016-04-14Bibliographically approved

Open Access in DiVA

fulltext(807 kB)26 downloads
File information
File name FULLTEXT01.pdfFile size 807 kBChecksum SHA-512
Type fulltextMimetype application/pdf

Other links

Publisher's full text

Search in DiVA

By author/editor
Verho, OscarBäckvall, Jan-Erling
By organisation
Department of Organic Chemistry
In the same journal
Journal of Organic Chemistry
Organic Chemistry

Search outside of DiVA

GoogleGoogle Scholar
Total: 26 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 77 hits
ReferencesLink to record
Permanent link

Direct link