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Coordination Behaviour of a Hexadentate 1,1′-Ferrocenylene-Bridged Bisphosphole towards Coinage Metal Centres
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics. (Orthaber)ORCID iD: 0000-0001-5403-9902
University of Kassel, Institute of Chemistry and Center for Interdisciplinary Nanostructure Science and Technology (CINSaT), Heinrich-Plett-Strasse 40, 34132 Kassel, Germany,.
Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS Université de Rennes 1, Campus de Beaulieu, 35042 Rennes CEDEX, France.
Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS Université de Rennes 1, Campus de Beaulieu, 35042 Rennes CEDEX, France.
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2014 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-0682, Vol. 2014, no 10, 1751-1759 p.Article in journal (Refereed) Published
Abstract [en]

We describe the synthesis of a ferrocenylene-bridged bis[2,5-bis(2-pyridyl)]phosphole ligand that shows additional rotational degrees of freedom relative to its previously described p-phenylene-bridged congener. The coordination behaviour of this ferrocenylene-based bis-N,P,N pincer towards coinage metal centres MI with M = Cu and Au was explored, revealing different coordination modes with and without involvement of N donation. Upon coordination of AuI metal centres, different isomers of a bimetallic AuI complex were isolated in the crystalline solid state that showed (or did not) intramolecular aurophilic interaction. Aurophilic as well as Au–N interactions have been investigated by means of ab initio calculations.

Place, publisher, year, edition, pages
Wiley-VCH Verlagsgesellschaft, 2014. Vol. 2014, no 10, 1751-1759 p.
Keyword [en]
Gold;P ligands;Sandwich complexes;Coordination modes;Ab initio calculations
National Category
Inorganic Chemistry
Research subject
Chemistry with specialization in Inorganic Chemistry
URN: urn:nbn:se:uu:diva-221878DOI: 10.1002/ejic.201301281ISI: 000333486900022OAI: diva2:710268
Available from: 2014-04-06 Created: 2014-04-06 Last updated: 2014-05-13Bibliographically approved

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