Electrochemical quartz crystal microbalance study of polyelectrolyte film growth under anodic conditions
2013 (English)In: Applied Surface Science, ISSN 0169-4332, E-ISSN 1873-5584, Vol. 280, 783-790 p.Article in journal (Refereed) Published
Coating hard materials such as Pt with soft polymers like poly-l-lysine is a well-established technique for increasing electrode biocompatibility. We have combined quartz crystal microgravimetry with dissipation with electrochemistry (EQCM-D) to study the deposition of PLL onto Pt electrodes under anodic potentials. Our results confirm the change in film growth over time previously reported by others. However, the dissipation data suggest that, after the short initial phase of the process, the rigidity of the film increases with time, rather than decreasing, as previously proposed. In addition to these results, we discuss how gas evolution from water electrolysis and Pt etching in electrolytes containing Cl− affect EQCM-D measurements, how to recognize these effects, and how to reduce them. Despite the challenges of using Pt as an anode in this system, we demonstrate that the various electrochemical processes can be understood and that PLL coatings can be successfully electrodeposited.
Place, publisher, year, edition, pages
Elsevier , 2013. Vol. 280, 783-790 p.
Quartz crystal microgravimetry, QCM, Electrochemistry, Poly-L-lysine, Platinum electrode, Film growth
Engineering and Technology
IdentifiersURN: urn:nbn:se:liu:diva-95934DOI: 10.1016/j.apsusc.2013.05.062ISI: 000321045700117OAI: oai:DiVA.org:liu-95934DiVA: diva2:641775
Funding Agencies|Swedish Research Council (Vetenskapsradet)|325-2008-7537621-2007-3983|Bo Liedberg and the Molecular Physics Group at Linkoping University for access to equipment||Carl Trygger Foundation and The Swedish Foundation for Strategic Research||2013-08-192013-08-122015-06-15