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A Ferrocene-Porphyrin Ligand for Multi-Transduction Chemical Sensor Development
University of Roma Tor Vergata, Italy St Petersburg State University, Russia.
University of Roma Tor Vergata, Italy.
University of Roma Tor Vergata, Italy.
Linköping University, Department of Physics, Chemistry and Biology, Biosensors and Bioelectronics. Linköping University, The Institute of Technology.
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2013 (English)In: Sensors, ISSN 1424-8220, E-ISSN 1424-8220, Vol. 13, no 5, 5841-5856 p.Article in journal (Refereed) Published
Abstract [en]

5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin acceptor sub-units was considered. The simultaneously measured optical and potentiometric responses of solvent polymeric membranes based on H2TFcP permitted the detection of lead ions in sample solutions, in the concentration range from 2.7 × 10−7 to 3.0 × 10−3 M. The detection limit of lead determination was 0.27 μM, low enough to perform the direct analysis of Pb2+ in natural waters.

Place, publisher, year, edition, pages
MDPI , 2013. Vol. 13, no 5, 5841-5856 p.
Keyword [en]
porphyrin-ferrocene ligand; opto-potentiometric transduction; transition metals detection
National Category
Engineering and Technology
Identifiers
URN: urn:nbn:se:liu:diva-96145DOI: 10.3390/s130505841ISI: 000319445600027OAI: oai:DiVA.org:liu-96145DiVA: diva2:640728
Available from: 2013-08-14 Created: 2013-08-14 Last updated: 2017-12-06

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Lundström, Ingemar

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