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Development of iridium-catalyzed asymmetric hydrogenation: New catalysts, new substrate scope
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - BMC, Synthetical Organic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - BMC, Synthetical Organic Chemistry.
2012 (English)In: Journal of Organometallic Chemistry, ISSN 0022-328X, E-ISSN 1872-8561, Vol. 714, 3-11 p.Article, review/survey (Refereed) Published
Abstract [en]

A review. The asym. hydrogenation of olefins is a tremendously powerful tool used to synthesize chiral mols. The field was pioneered using rhodium- and ruthenium- based catalysts; however, catalysts based on both of these metals suffer from limitations, such as the need for directing substituents near or even adjacent to the olefin. Iridium-based catalysts do not suffer from this flaw and can thus hydrogenate a wide variety of olefins, including some tetra substituted ones. It is also possible for iridium-based catalysts to hydrogenate hetero-π bonds such as those found in heteroarom. rings. This review summarizes the contributions made to this field by the authors in the past few years. [on SciFinder(R)]

Place, publisher, year, edition, pages
2012. Vol. 714, 3-11 p.
Keyword [en]
review iridium catalyst asym hydrogenation alkene heteroarom
National Category
Organic Chemistry
Research subject
Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-187584DOI: 10.1016/j.jorganchem.2012.04.002ISI: 000306239400003OAI: oai:DiVA.org:uu-187584DiVA: diva2:575232
Available from: 2012-12-10 Created: 2012-12-07 Last updated: 2017-12-07Bibliographically approved

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Cadu, AlbanAndersson, Pher G.

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