Optical properties of Mg-doped VO2: Absorption measurements and hybrid functional calculations
2012 (English)In: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 101, no 20, 201902- p.Article in journal (Refereed) Published
Mg-doped VO2 thin films with thermochromic properties were made by reactive DC magnetron co-sputtering onto heated substrates, and spectral absorption was recorded at room temperature in the 0.5 < <(h)over bar>omega < 3.5 eV energy range. Clear evidence was found for a widening of the main band gap from 1.67 to 2.32 eV as the Mg/(V + Mg) atomic ratio went from zero to 0.19, thereby significantly lowering the luminous absorption. This technologically important effect could be reconciled with spin-polarized density functional theory calculations using the Heyd-Scuseria-Ernzerhof [Heyd et al., J. Chem. Phys. 118, 8207 (2003); ibid. 124, 219906 (2006)] hybrid functional. Specifically, the calculated luminous absorptance decreased when the Mg/(V + Mg) ratio was increased from 0.125 to 0.250.
Place, publisher, year, edition, pages
American Institute of Physics (AIP), 2012. Vol. 101, no 20, 201902- p.
Condensed Matter Physics Engineering and Technology Inorganic Chemistry
Research subject Engineering Science with specialization in Solid State Physics; Chemistry with specialization in Inorganic Chemistry
IdentifiersURN: urn:nbn:se:uu:diva-187522DOI: 10.1063/1.4766167ISI: 000311477500009OAI: oai:DiVA.org:uu-187522DiVA: diva2:575069