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Plasmon-induced near-infrared electrochromism based on transparent conducting nanoparticles: Approximate performance limits
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics. (Fasta tillståndets fysik, Solid State Physics)ORCID iD: 0000-0002-8279-5163
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.
2012 (English)In: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 101, no 7, 071903- p.Article in journal (Refereed) Published
Abstract [en]

Electrochromism can be induced in electrochemically post-treated nanoparticles of wide band gap transparent conductors. We model this recently observed phenomenon by effective medium theory applied to nanoparticles of In2O3:Sn, which are represented as a free-electron plasma with tin ions screened according to the random phase approximation corrected for electron exchange. This semi-quantitative theory is used to derive approximate performance limits showing that high luminous transmittance (e.g., 60%) can be combined with efficient absorption of solar energy and concomitant low solar transmittance (similar to 34%), thereby documenting that plasmonic electrochromism is of interest for energy efficient fenestration.

Place, publisher, year, edition, pages
2012. Vol. 101, no 7, 071903- p.
National Category
Physical Sciences Engineering and Technology
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
URN: urn:nbn:se:uu:diva-183232DOI: 10.1063/1.4739792ISI: 000308263100022OAI: oai:DiVA.org:uu-183232DiVA: diva2:562689
Available from: 2012-10-25 Created: 2012-10-23 Last updated: 2017-12-07Bibliographically approved

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Li, ShuyiNiklasson, Gunnar AGranqvist, Claes-Göran

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