Electronic structure of tris(8-hydroxyquinoline) aluminum thin films in the pristine and reduced states
1999 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 111, no 5, 2157-2163 p.Article in journal (Refereed) Published
The electronic structure of tris(8-hydroxyquinoline) aluminum (Alq(3)) has been studied in the pristine molecular solid state as well as upon interaction (doping) with potassium and lithium. We discuss the results of a joint theoretical and experimental investigation, based on a combination of x-ray and ultraviolet photoelectron spectroscopies with quantum-chemical calculations at the density functional theory level. Upon doping, each electron transferred from an alkali metal atom is stored on one of the three ligands of the Alq(3) molecule, resulting in a new spectral feature (peak) in the valence band that evolves uniformly when going from a doping level of one to three metal atoms per Alq(3) molecule. (C) 1999 American Institute of Physics. [S0021-9606(99)50628-4].
Place, publisher, year, edition, pages
American Institute of Physics (AIP) , 1999. Vol. 111, no 5, 2157-2163 p.
Engineering and Technology
IdentifiersURN: urn:nbn:se:liu:diva-81302DOI: 10.1063/1.479486ISI: 000081698700043OAI: oai:DiVA.org:liu-81302DiVA: diva2:551453