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Photon Upconversion on Dye-Sensitized Nanostructured ZrO2 Films
Uppsala University.
Uppsala University.ORCID iD: 0000-0002-4782-4969
Uppsala University.
2011 (English)In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 115, no 46, 23226-23232 p.Article in journal (Refereed) Published
Abstract [en]

Photon upconversion based on sensitized triplet?triplet annihilation has been observed on nanocrystalline ZrO2 films cosensitized with platinum(II) octaethylporphyrin (triplet sensitizer) and 9,10-diphenylanthracene (singlet emitter) under sunlight-like conditions (noncoherent excitation source, excitation light intensity as low as 5 mW/cm2). Time-resolved emission measurements showed a fast rise of the upconverted signal (≀10 ns), suggesting that triplet energy migration most probably occurs through a ?static? Dexter mechanism. To the best of our knowledge, this is the first observation of photon upconversion based on sensitized triplet?triplet annihilation on a sensitized mesoporous metal oxide. Implementation of similar systems in dye-sensitized solar cells would increase the maximum theoretical efficiency of these devices from 30% to over 40%.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2011. Vol. 115, no 46, 23226-23232 p.
Keyword [en]
METAL-OXIDE NANOPARTICLES; TRIPLET ENERGY-TRANSFER; POLYMER-FILMS; SOLAR-CELLS; SURFACES; PHOTOCHEMISTRY; PHOTOPHYSICS; LIGHT; BLUE
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-51580DOI: 10.1021/jp209774pISI: 000297001000069OAI: oai:DiVA.org:kth-51580DiVA: diva2:464769
Note
QC 20111221Available from: 2011-12-21 Created: 2011-12-13 Last updated: 2017-12-08Bibliographically approved

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Lissau 2011 JPhysChemC v115 p23226(1483 kB)787 downloads
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