Change search
ReferencesLink to record
Permanent link

Direct link
Peroxide-based ATMP refining of spruce: energy efficiency, fibre properties and pulp quality
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences, Engineering and Mathematics.
Paper & Fibre Res Inst PFI, NO-7491 Trondheim, Norway.
Norske Skog Saugbrugs, NO-1756 Halden, Norway.
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences, Engineering and Mathematics.
2011 (English)In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, Vol. 26, no 1, 47-63 p.Article in journal (Refereed) Published
Abstract [en]

Pilot scale refining of White spruce using a modified TMP refining process (ATMP - Advanced Thermomechanical Pulp) was studied. ATMP combines selective wood disintegration by mechanical pretreatment and refining at elevated intensity with chemical treatment after defibration (in this study hydrogen peroxide, alone and in combination with alkali). The electrical energy efficiency and pulp quality using ATMP were evaluated and compared to a conventional TMP process. One goal was to retain the combination of optical properties and strength of typical TMP. Fibre properties (structural dimensions, external and internal fibre development) as well as the amount of split fibres resulting from TMP and ATMP processes were compared. The results indicate an electrical energy efficiency improvement potential of 0.65 MWh/odt (34%) at tensile index 30 N.m/g of ATMP compared to reference TMP. All ATMP pulps retained their TMP character, i.e. the relationships between light scattering coefficient, density, elongation properties and strength that are important for printing paper. ATMP had a significantly lower content of shives and higher external and internal fibre development compared to TMP at equal energy application. The long fibre fraction of ATMP also contained significantly higher amount of split fibres. The brightness of ATMP produced with addition of hydrogen peroxide (28 kg/odt) and magnesium hydroxide (14 kg/odt) was 14 ISO % higher compared to TMP.

Place, publisher, year, edition, pages
2011. Vol. 26, no 1, 47-63 p.
Keyword [en]
ATMP; TMP; Energy reduction; Fibre characterisation; Hydrogen peroxide; Magnesium hydroxide; Refiner bleaching
National Category
Paper, Pulp and Fiber Technology
Identifiers
URN: urn:nbn:se:miun:diva-13846DOI: 10.3183/NPPRJ-2011-26-01-p047-063ISI: 000293770200005ScopusID: 2-s2.0-79955447235OAI: oai:DiVA.org:miun-13846DiVA: diva2:419562
Available from: 2011-05-27 Created: 2011-05-27 Last updated: 2012-03-21Bibliographically approved
In thesis
1. ATMP Process: Improved Energy Efficiency in TMP Refining Utilizing Selective Wood Disintegration and Targeted Application of Chemicals
Open this publication in new window or tab >>ATMP Process: Improved Energy Efficiency in TMP Refining Utilizing Selective Wood Disintegration and Targeted Application of Chemicals
2011 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

This thesis is focused on the novel wood chip refining process called AdvancedThermomechanical Pulp (ATMP) refining. ATMP consists of mechanical pretreatmentof chips in Impressafiner and Fiberizer prior to first stage refining atincreased intensity. Process chemicals (this study was concentrated on hydrogenperoxide and magnesium hydroxide) are introduced into the first stage refiner.It is known that the use of chemicals in TMP process and first stage refining atelevated intensity can reduce the energy demands of refining. The downside is thatthey also alter the character of the produced pulp. Reductions in fibre length andtear index are usually the consequences of refining at elevated intensity. Additionof chemicals usually leads to reduction of the light scattering coefficient. Usingstatistical methods it was shown that it is possible to maintain the TMP character ofthe pulp using the ATMP process. This is explained by a separation of thedefibration and the fibre development phases in refining. This separation allowsdefibration of chips to fibres and fibre bundles without addition of chemicals orincrease in refining intensity. Chemicals are applied in the fibre developmentphase only (first stage refiner). The energy demand in refining to reach tensileindex of 25 Nm/g was reduced by up to 1.1 MWh/odt (42 %) using the ATMPprocess on Loblolly pine. The energy demand in refining of White spruce, requiredto reach tensile index of 30 Nm/g, was reduced by 0.65 MWh/odt (37%).Characterizations of individual fibre properties, properties of sheets made fromlong fibre fractions and model fibre sheets with different fines fractions werecarried out. It was established that both the process equipment configuration (i.e.the mechanical pre‐treatment and the elevated refining intensity) and the additionof process chemicals in the ATMP process influence fibre properties such as external and internal fibrillation as well as the amount of split fibres. Improvementof these properties translated into improved properties of sheets, made from thelong fibre fractions of the studied pulps. The quality of the fines fraction alsoimproved. However, the mechanisms of improvement in the fines quality seem tobe different for fines, generated using improved process configuration andaddition of process chemicals. The first type of fines contributed to better bondingof model long fibre sheets through the densification of the structure. Fines whichhave been influenced by the addition of the process chemicals seemed in additionto improve bonding between long fibres by enhancing the specific bond strength.The improved fibre and fines properties also translated into better airpermeability and surface roughness of paper sheets, properties which areespecially important for supercalendered (SC) printing paper. The magnitude offibre roughening after moistening was mainly influenced by the processequipment configuration while the addition of process chemicals yielded lowestfinal surface roughness due to the lowest initial surface roughness. There was nodifference in how fines fractions from the studied processes influenced the fibreroughening. However, fines with better bonding yielded model fibre sheets withhigher PPS, probably due to their consolidation around fibre joints. Hence, thedecrease in PPS can probably be attributed to the improvements in the long fibrefraction properties while the improvement of fines quality contributed to thereduction of air permeability.The process chemicals, utilized in the ATMP process (Mg(OH)2 and H2O2) alsoproved to be an effective bleaching system. Comparable increases in brightnesscould be reached using the ATMP process and conventional tower bleaching.Maximum brightness of the pulp was reached after approximately 10 minutes ofhigh‐consistency storage after refining or 40 minutes of conventional bleaching.This study was conducted using a pilot scale refiner system operated as a batchprocess. Most of the experiments were performed using White spruce (Piceaglauca). In Paper I, Loblolly pine (Pinus taeda) was used. It is believed that theresults presented in this thesis are valid for other softwood raw materials as well,but this limitation should be considered.

Place, publisher, year, edition, pages
Sundsvall: Mid Sweden University, 2011. 119 p.
Series
Mid Sweden University doctoral thesis, ISSN 1652-893X ; 108
Keyword
ATMP, TMP, Hydrogen Peroxide, Magnesium Hydroxide, Mechanical Pre-Treatment, Fibre Characterisation, Refiner Bleaching, SC Paper, Newsprint
National Category
Paper, Pulp and Fiber Technology
Identifiers
urn:nbn:se:miun:diva-13844 (URN)978-91-86694-34-0 (ISBN)
Public defence
2011-05-05, 10:18 (English)
Supervisors
Available from: 2011-05-27 Created: 2011-05-27 Last updated: 2012-07-30Bibliographically approved

Open Access in DiVA

fulltext(744 kB)582 downloads
File information
File name FULLTEXT02.pdfFile size 744 kBChecksum SHA-512
f078b6ba24fad50526ee853c5682d25e3ff29c9e4e4310fa8881177c29ba5ceb78cbf3c340ba0a9a306189f9ab407d780a41ae584c48e7c8f2aadf40f520d60f
Type fulltextMimetype application/pdf

Other links

Publisher's full textScopus

Search in DiVA

By author/editor
Gorski, DmitriEngstrand, Per
By organisation
Department of Natural Sciences, Engineering and Mathematics
In the same journal
Nordic Pulp & Paper Research Journal
Paper, Pulp and Fiber Technology

Search outside of DiVA

GoogleGoogle Scholar
Total: 582 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 840 hits
ReferencesLink to record
Permanent link

Direct link