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Structure sensitivity of double inner-shell holes in sulfur-containing molecules
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Soft X-Ray Physics.
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2011 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 83, no 2, 022506- p.Article in journal (Refereed) Published
Abstract [en]

To demonstrate the structure sensitivity of double inner-shell hole spectroscopy, we have measured energies of H2S2+, SO22+, and CS22+ with the two vacancies in the sulfur 2p shell using a multielectron coincidence technique combined with synchrotron radiation. We describe how to extract intrinsic chemical information which is masked by the orbital relaxation effect in conventional core-level photoelectron spectroscopy.

Place, publisher, year, edition, pages
2011. Vol. 83, no 2, 022506- p.
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Physical Sciences
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URN: urn:nbn:se:uu:diva-149572DOI: 10.1103/PhysRevA.83.022506ISI: 000287482500008OAI: oai:DiVA.org:uu-149572DiVA: diva2:405178
Available from: 2011-03-21 Created: 2011-03-21 Last updated: 2016-02-29Bibliographically approved

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