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Disordered plasmonic system with dense copper nano-island morphology
Umeå University, Faculty of Science and Technology, Department of Physics.ORCID iD: 0000-0002-0839-4556
Istituto Italiano di Tecnologia, Genova, Italy; Dipartimento di Fisica, Università della Calabria, Rende, CS, Italy.
College of Optical Science and Engineering, Zhejiang University, Hangzhou, China.
Istituto Italiano di Tecnologia, Genova, Italy.
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2025 (English)In: Nanophotonics, ISSN 2192-8606, E-ISSN 2192-8614Article in journal (Refereed) Epub ahead of print
Abstract [en]

Dry synthesis is a highly versatile method for the fabrication of nanoporous metal films, since it enables easy and reproducible deposition of single or multi-layers of nanostructured materials that can find intriguing applications in plasmonics, photochemistry and photocatalysis, to name a few. Here, we extend the use of this methodology to the preparation of copper nano-islands that represent an affordable and versatile example of disordered plasmonic substrates. Although the island morphology is disordered, the high density of these nanostructures with large surface area results in a good homogeneity on a macroscale, which is beneficial for plasmonic applications such as bio-sensing and photo-catalysis. With cathodoluminescence and electron-energy-loss spectroscopies we confirm the nano-islands as sources of the local field enhancement and identify the plasmonic resonance bands in the visible and near-infrared spectral range. The decay dynamics of the plasmonic signal are slower in the nano-island as compared to bulk copper films, which can be rationalized by a reduced energy dissipation in the nano-island films. Our study demonstrates a robust and lithography-free fabrication pathway to obtain nanostructured plasmonic copper substrates that represent a highly versatile low-cost alternative for future applications ranging from sensing to photochemistry and photocatalysis.

Place, publisher, year, edition, pages
2025.
Keywords [en]
EELS, cathodoluminescence, SHG, pump-probe, nano islands, nanoporous
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:umu:diva-238190DOI: 10.1515/nanoph-2024-0743OAI: oai:DiVA.org:umu-238190DiVA, id: diva2:1954732
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EU, Horizon 2020Available from: 2025-04-25 Created: 2025-04-25 Last updated: 2025-04-28

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