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Reducing plastic anisotropy through stress induced martensitic transformation in an additively manufactured metastable medium entropy alloy
Department of Industrial and Materials Science, Chalmers University of Technology, SE-41296, Göteborg, Sweden.
Bundesanstalt für Materialforschung und–prüfung (BAM), Unter den Eichen 87, 12205, Berlin, Germany.
Department of Industrial and Materials Science, Chalmers University of Technology, SE-41296, Göteborg, Sweden.
Department of Industrial and Materials Science, Chalmers University of Technology, SE-41296, Göteborg, Sweden; Department of Materials Science and Engineering, KTH Royal Institute of Technology, Brinellvägen 23, Stockholm, 10044, Sweden.
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2025 (English)In: Materials Science & Engineering: A, ISSN 0921-5093, E-ISSN 1873-4936, Vol. 933, article id 148308Article in journal (Refereed) Published
Abstract [en]

Powder bed fusion laser beam (PBF-LB) is particularly effective for fabricating compositionally complex alloys such as high-entropy alloys (HEAs) or medium-entropy alloys (MEAs). Fabricating non-equiatomic metastable MEAs using PBF-LB can lead to the formation of unique microstructures that enhance the mechanical performance of these alloys. Nevertheless, plastic anisotropy in materials prepared by additive manufacturing routes including PBF-LB remains to be a technical challenge. This work presents the fabrication of a metastable non-equiatomic Co45Cr25(FeNi)30 MEA using PBF-LB. As-printed samples exhibited the formation of nano-scaled ε-martensite (HCP) phase along with the FCC phase. The HCP phase exhibited Shoji-Nishiyama orientation relationship with the FCC phase. High energy synchrotron X-ray diffraction (HEXRD) and electron backscatter diffraction (EBSD) in-situ tensile testing were employed to investigate the influence of the HCP phase on the alloy's deformation behavior. The presence of the HCP phase initiates stress-induced martensitic transformation well below the macroscopic yield strength. This transformation led to the non-linear stress and strain response for the FCC phase. Further straining resulted in significant load partitioning, with the HCP phase taking the majority of the load as it formed, significantly strain hardening the alloy and reducing the plastic anisotropy induced by texture in the as-printed material.

Place, publisher, year, edition, pages
Elsevier Ltd , 2025. Vol. 933, article id 148308
Keywords [en]
Powder bed fusion-laser beam, Medium entropy alloys, Phase transformation, Load partitioning, Synchrotron X-ray diffraction
National Category
Metallurgy and Metallic Materials
Research subject
Engineering Materials
Identifiers
URN: urn:nbn:se:ltu:diva-112466DOI: 10.1016/j.msea.2025.148308Scopus ID: 2-s2.0-105002225775OAI: oai:DiVA.org:ltu-112466DiVA, id: diva2:1953421
Funder
Vinnova, 2022-03076Swedish Research Council, 2020-0619
Note

Validerad;2025;Nivå 2;2025-04-22 (u5);

Full text license: CC BY 4.0;

Available from: 2025-04-22 Created: 2025-04-22 Last updated: 2025-04-22Bibliographically approved

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