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Determination of intrinsic scattering and absorption coefficients of light diffusing materials: application of a spectral projected gradient method
Universidad de Costa Rica.ORCID iD: 0000-0001-8460-8491
Universidad de Costa Rica.ORCID iD: 0009-0008-3411-7203
University of Cambridge.ORCID iD: 0000-0003-3849-3835
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Materials Science and Engineering, Solid State Physics.ORCID iD: 0000-0002-8279-5163
2024 (English)In: Journal of Modern Optics, ISSN 0950-0340, E-ISSN 1362-3044, Vol. 71, no 16-18, p. 640-664Article in journal (Refereed) Published
Abstract [en]

We explore a novel method to obtain scattering and absorption (S&A) coefficients of inhomogeneous materials from measurements of regular transmittance and specular reflectance. We use a Spectral Projected Gradient Method (SPGM) to invert experimental spectra. The SPGM method requires an initial approximation to the S&A coefficients, which is needed to ensure convergence to an optimized solution. We discuss problems associated with multiple solutions and conditions for the obtained optimal solution to be a good approximation to the physical one. We present results for TiO2/polyvinylpyrrolidone (PVP)-water, plasmonic Au/PVP-water and ferromagnetic Fe3O4/PVP-water materials. The obtained S&A coefficients indicate that these materials are dilute suspensions of dense particle clusters in the dependent scattering regime. We argue that the SPGM gives physically realistic solutions for this class of materials. The SPGM has the advantages that it is much less expensive in computational terms and easier to implement than previously used simulated annealing methods.

Place, publisher, year, edition, pages
Taylor & Francis, 2024. Vol. 71, no 16-18, p. 640-664
Keywords [en]
Light scattering, light absorption, gold, iron oxide, titanium dioxide, radiative transfer
National Category
Atom and Molecular Physics and Optics
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
URN: urn:nbn:se:uu:diva-550515DOI: 10.1080/09500340.2024.2448213ISI: 001395490700001Scopus ID: 2-s2.0-85214705350OAI: oai:DiVA.org:uu-550515DiVA, id: diva2:1937935
Available from: 2025-02-16 Created: 2025-02-16 Last updated: 2025-02-17Bibliographically approved

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Vargas, William E.Abarca-Quesada, Denis A.Wang, JunxinNiklasson, Gunnar A.
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