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Interplay between disorder and electronic correlations in compositionally complex alloys
Univ West Bohemia, New Technol Res Ctr, Plzen, Czech Republic.;Munich Univ Appl Sci HM, Dept Appl Sci & Mechatron, Munich, Germany..
Univ West Bohemia, New Technol Res Ctr, Plzen, Czech Republic..
Ecole Polytech Fed Lausanne, Inst Phys, Lausanne, Switzerland..
Ecole Polytech Fed Lausanne, Inst Phys, Lausanne, Switzerland..ORCID iD: 0000-0003-2414-2575
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2024 (English)In: Nature Communications, E-ISSN 2041-1723, Vol. 15, no 1, article id 7983Article in journal (Refereed) Published
Abstract [en]

Owing to their exceptional mechanical, electronic, and phononic transport properties, compositionally complex alloys, including high-entropy alloys, represent an important class of materials. However, the interplay between chemical disorder and electronic correlations, and its influence on electronic structure-derived properties, remains largely unexplored. This is addressed for the archetypal CrMnFeCoNi alloy using resonant and valence band photoemission spectroscopy, electrical resistivity, and optical conductivity measurements, complemented by linear response calculations based on density functional theory. Utilizing dynamical mean-field theory, correlation signatures and damping in the spectra are identified, highlighting the significance of many-body effects, particularly in states distant from the Fermi edge. Electronic transport remains dominated by disorder and potentially short-range order, especially at low temperatures, while visible-spectrum optical conductivity and high-temperature transport are influenced by short quasiparticle lifetimes. These findings improve our understanding of element-specific electronic correlations in compositionally complex alloys and facilitate the development of advanced materials with tailored electronic properties. Compositionally complex alloys have attracted significant attention recently, but the role of electronic correlations in these materials is unknown. Redka et al. study the CrMnFeCoNi alloy using a combination of experimental and theoretical techniques, revealing strong correlation effects far from the Fermi edge.

Place, publisher, year, edition, pages
Springer Nature, 2024. Vol. 15, no 1, article id 7983
National Category
Condensed Matter Physics
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URN: urn:nbn:se:uu:diva-540147DOI: 10.1038/s41467-024-52349-8ISI: 001312845900031PubMedID: 39266550OAI: oai:DiVA.org:uu-540147DiVA, id: diva2:1905226
Funder
German Research Foundation (DFG), 528706678EU, Horizon 2020, 945339Available from: 2024-10-11 Created: 2024-10-11 Last updated: 2024-10-11Bibliographically approved

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