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The effects of copper addition on phase composition in (CrFeCo)1-yNy multicomponent thin films
Linköpings universitet, Tunnfilmsfysik.
Linköpings universitet, Tunnfilmsfysik.ORCID iD: 0000-0002-2696-4372
Linköpings universitet, Plasma och ytbeläggningsfysik.ORCID iD: 0000-0002-6602-7981
Linköpings universitet, Tunnfilmsfysik.ORCID iD: 0000-0002-3059-7392
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2022 (English)In: Applied Surface Science, ISSN 0169-4332, E-ISSN 1873-5584, Vol. 572, article id 151315Article in journal (Refereed) Published
Abstract [en]

The Cantor alloy CrFeCoMnNi is generally fcc structured, but moderate changes in the composition can have a large influence on the phase formation. The aim of this study was to understand the changes brought on in low-nitrogen-containing (CrFeCo)1-yNy thin films with y = 0.19 on the addition of copper, an interesting metal in terms of atomic size and nitride formation enthalpy. (CrFeCoCux)1-yNy films were grown by reactive magnetron sputtering. The amount of copper in the films was increased from x = 0 to x = 0.15 to study competitive phase formation. Without Cu, two-phase fcc + bcc films were obtained. The addition of Cu was found to stabilize the bcc structure despite the fact that Cu as a pure metal is fcc. Nanoindentation tests showed slight increase in hardness with initial Cu addition from 11 GPa to 13.7 ± 0.2 GPa. The occurrence of pile up as opposed to cracking is an indication of the film’s ductility.

Place, publisher, year, edition, pages
Elsevier, 2022. Vol. 572, article id 151315
Keywords [en]
Multicomponent, Coating, Magnetron sputtering, High entropy alloy
National Category
Other Materials Engineering
Identifiers
URN: urn:nbn:se:uu:diva-537650DOI: 10.1016/j.apsusc.2021.151315ISI: 000718301200003OAI: oai:DiVA.org:uu-537650DiVA, id: diva2:1894579
Funder
Vinnova, 2016-05156Linköpings universitet, 2009 00971Knut and Alice Wallenberg Foundation, 2020.0196Swedish Research Council, C0514401Swedish Foundation for Strategic Research, RIF14-0053Available from: 2024-09-03 Created: 2024-09-03 Last updated: 2024-09-05Bibliographically approved

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Shu, RuiBoyd, Robertle Febvrier, ArnaudEklund, Per
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