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Enamine/Transition Metal Combined Catalysis: Catalytic Transformations Involving Organometallic Electrophilic Intermediates
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.ORCID iD: 0000-0002-5108-6487
Mid Sweden University, Faculty of Science, Technology and Media, Department of Natural Sciences.
2019 (English)In: Topics in Current Chemistry, ISSN 2365-0869, Vol. 377, no 6, article id 38Article in journal (Refereed) Published
Abstract [en]

The concept of merging enamine activation catalysis with transition metal catalysis is an important strategy, which allows for selective chemical transformations not accessible without this combination. The amine catalyst activates the carbonyl compounds through the formation of a reactive nucleophilic enamine intermediate and, in parallel, the transition metal activates a wide range of functionalities such as allylic substrates through the formation of reactive electrophilic π-allyl-metal complex. Since the first report of this strategy in 2006, considerable effort has been devoted to the successful advancement of this technology. In this chapter, these findings are highlighted and discussed. 

Place, publisher, year, edition, pages
2019. Vol. 377, no 6, article id 38
Keywords [en]
Amino catalysis, Combined catalysis, Enamine catalysis, Organocatalysis, Transition metal catalysis
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:miun:diva-38184DOI: 10.1007/s41061-019-0267-yISI: 000496659200001PubMedID: 31732819Scopus ID: 2-s2.0-85075114368OAI: oai:DiVA.org:miun-38184DiVA, id: diva2:1383669
Note

This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/)

Available from: 2020-01-08 Created: 2020-01-08 Last updated: 2020-01-16Bibliographically approved

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