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Bandgap engineering in Mn3TeO6: giant irreversible bandgap reduction triggered by pressure
Uppsala University, Disciplinary Domain of Science and Technology, Earth Sciences, Department of Earth Sciences, Mineralogy Petrology and Tectonics.ORCID iD: 0000-0002-7749-0402
Swedish Museum Nat Hist, Dept Geosci, S-10405 Stockholm, Sweden.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics. Karpovs Inst Phys Chem, Dept Inorgan Mat, Moscow 105046, Russia.ORCID iD: 0000-0002-7177-8464
TU Wien, Inst Chem Technol & Analyt, Getreidemarkt 9-164-SC, A-1060 Vienna, Austria.ORCID iD: 0000-0001-5235-9910
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2019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 80, p. 12000-12003Article in journal (Refereed) Published
Abstract [en]

In this study, the bandgap energy of the multiferroic oxide Mn3TeO6 is successfully reduced by similar to 39% from 3.15 eV to 1.86 eV, accompanied by a phase transition at high pressures. The high-pressure phase with smaller bandgap energy is quenchable to ambient conditions and represents a promising light-harvesting material for photovoltaic applications.

Place, publisher, year, edition, pages
2019. Vol. 55, no 80, p. 12000-12003
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Physical Chemistry
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URN: urn:nbn:se:uu:diva-397942DOI: 10.1039/c9cc04821aISI: 000496529500030PubMedID: 31524904OAI: oai:DiVA.org:uu-397942DiVA, id: diva2:1382331
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Swedish Research CouncilAvailable from: 2020-01-02 Created: 2020-01-02 Last updated: 2020-01-02Bibliographically approved

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