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Is basicity the sole criterion for attaining high carbon dioxide capture in deep-eutectic solvents?
Umeå University, Faculty of Science and Technology, Department of Chemistry.ORCID iD: 0000-0002-7102-5198
Umeå University, Faculty of Science and Technology, Department of Chemistry.
2020 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 22, no 3, p. 966-970Article in journal (Refereed) Published
Abstract [en]

A critical analysis of the role of Hammett basicity (H−) and aqueous basicity (pKa) in CO2 uptake in deep-eutectic solvents (DESs) suggests that neither H− nor pKa correlates with the CO2 w/w% capacity in the studied DESs. Instead, strong “synergistic interactions” between donor and acceptor moieties satisfactorily relate to the w/w% of CO2 in DESs.

Place, publisher, year, edition, pages
The Royal Society of Chemistry , 2020. Vol. 22, no 3, p. 966-970
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Other Environmental Engineering Energy Systems
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URN: urn:nbn:se:umu:diva-166621DOI: 10.1039/C9CP06017KISI: 000509371400002PubMedID: 31848547OAI: oai:DiVA.org:umu-166621DiVA, id: diva2:1380514
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Bio4EnergyAvailable from: 2019-12-19 Created: 2019-12-19 Last updated: 2020-02-21Bibliographically approved

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