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Facile synthesis of silver alkynide cluster and coordination polymers using picolinic acid as a co-ligand
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Synthetic Molecular Chemistry.ORCID iD: 0000-0002-8969-1236
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Synthetic Molecular Chemistry.ORCID iD: 0000-0001-5403-9902
2019 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 48, no 44, p. 16518-16524Article in journal (Refereed) Published
Abstract [en]

We describe five 1D-coordination polymers and two discrete silver clusters consisting of alkynides and picolinic carboxylates as co-ligands. In some cases, DMSO or EtOH further solvated the structural motifs. Utilising the sterically demanding tri-isopropylsilyl acetylene afforded a tridecanuclear cluster that possessed an unprecedented core with a silver center surrounded by six octahedrally arranged silver atoms.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2019. Vol. 48, no 44, p. 16518-16524
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-398424DOI: 10.1039/c9dt03697kISI: 000496535000035PubMedID: 31663564OAI: oai:DiVA.org:uu-398424DiVA, id: diva2:1376028
Funder
Stiftelsen Olle Engkvist ByggmästareSwedish Research CouncilAvailable from: 2019-12-06 Created: 2019-12-06 Last updated: 2019-12-06Bibliographically approved

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