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Buchwald Hartwig diversification of unprotected halotryptophans, halotryptophan containing tripeptides and the natural product barettin in aqueous conditions
Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland;Univ St Andrews, BSRC, St Andrews KY16 9ST, Fife, Scotland.
Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland;Univ St Andrews, BSRC, St Andrews KY16 9ST, Fife, Scotland.
Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland;Univ St Andrews, BSRC, St Andrews KY16 9ST, Fife, Scotland.
Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland;Univ St Andrews, BSRC, St Andrews KY16 9ST, Fife, Scotland.
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2019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 91, p. 13653-13656Article in journal (Refereed) Published
Abstract [en]

Blending synthetic biology and synthetic chemistry represents a powerful approach to diversity complex molecules. To further enable this, compatible synthetic tools are needed. We report the first Buchwald Hartwig amination reactions with unprotected halo-tryptophans under aqueous conditions and demonstrate this methodology is applicable also to the modification of unprotected tripeptides and the natural product barettin.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2019. Vol. 55, no 91, p. 13653-13656
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Physical Chemistry
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URN: urn:nbn:se:uu:diva-398021DOI: 10.1039/c9cc02554eISI: 000496533500033PubMedID: 31593201OAI: oai:DiVA.org:uu-398021DiVA, id: diva2:1375431
Funder
EU, FP7, Seventh Framework Programme, 614779 GenoChemeticsEU, Horizon 2020, 679849Available from: 2019-12-05 Created: 2019-12-05 Last updated: 2019-12-05Bibliographically approved

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