Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
A Novel Metastable Pentavalent Plutonium Solid Phase on the Pathway from Aqueous Plutonium(VI) to PuO2 Nanoparticles
HZDR, Inst Resource Ecol,Dresden, Germany; European Synchrotron, Rossendorf Beamline ESRF, Grenoble, France.
Lomonosov Moscow State Univ, Dept Chem, Moscow, Russia.ORCID iD: 0000-0002-7805-8670
HZDR, Inst Resource Ecol,Dresden, Germany; European Synchrotron, Rossendorf Beamline ESRF, Grenoble, France.
HZDR, Inst Resource Ecol,Dresden, Germany; European Synchrotron, Rossendorf Beamline ESRF, Grenoble, France.
Show others and affiliations
2019 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773Article in journal (Refereed) Published
Abstract [en]

Here we provide evidence that the formation of PuO2 nanoparticles from oxidized PuVI under alkaline conditions proceeds through the formation of an intermediate PuV solid phase, similar to NH4PuO2CO3, which is stable over a period of several months. For the first time, state‐of‐the‐art experiments at Pu M4 and at L3 absorption edges combined with theoretical calculations unambiguously allow to determine the oxidation state and the local structure of this intermediate phase.

Place, publisher, year, edition, pages
2019.
Keywords [en]
actinide chemistry, electronic-structure calculations, pentavalent plutonium, plutonium dioxide nanoparticles, Pu M-4 HERFD
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-397631DOI: 10.1002/anie.201911637ISI: 000494496600001PubMedID: 31621992OAI: oai:DiVA.org:uu-397631DiVA, id: diva2:1372226
Funder
EU, European Research Council, N759696Swedish Research Council, 2017-06465
Note

Early View: Online Version of Record before inclusion in an issue

Available from: 2019-11-22 Created: 2019-11-22 Last updated: 2019-11-22Bibliographically approved

Open Access in DiVA

fulltext(1398 kB)9 downloads
File information
File name FULLTEXT01.pdfFile size 1398 kBChecksum SHA-512
d4323eeb14061c2120b8972246a76836c43e00b5def2bebeb81e4a48be49018803b4b7699858177493cf50bc92d893e309cf7cba2a1016ca6dc677cf07ad69a4
Type fulltextMimetype application/pdf

Other links

Publisher's full textPubMed

Search in DiVA

By author/editor
Romanchuk, Anna YuGerber, EvgenyWeiss, StephanPopa, KarinScheinost, Andreas C.Butorin, Sergei M.
By organisation
Molecular and Condensed Matter Physics
In the same journal
Angewandte Chemie International Edition
Materials Chemistry

Search outside of DiVA

GoogleGoogle Scholar
Total: 9 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 8 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf