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Rearrangement and redistribution reaction of Ph2PCH2TMS with PhAsCl2 or AsCl3
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry. Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Synthetic Molecular Chemistry.ORCID iD: 0000-0002-8969-1236
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Synthetic Molecular Chemistry.ORCID iD: 0000-0002-9432-9231
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry. Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Synthetic Molecular Chemistry.ORCID iD: 0000-0001-5403-9902
2019 (English)In: Phosphorus Sulfur and Silicon and the Related Elements, ISSN 1042-6507, E-ISSN 1563-5325, Vol. 194, no 10, p. 967-971Article in journal (Refereed) Published
Abstract [en]

The attempted synthesis of bis(diphenylphosphinomethyl) phenylarsane and tris(diphenylphosphinomethyl) arsane through condensation of chloro arsanes and diphenyl (trimethylsilylmethyl) phosphane yielded a number of side products originating from migratory and redox-reactions in addition to the targeted ligands. An unexpected, 1,3,4-phosphadiarssolan-1-ium salt was obtained and crystallographically characterized as an A-shaped chlorido adduct. [GRAPHICS] .

Place, publisher, year, edition, pages
TAYLOR & FRANCIS LTD , 2019. Vol. 194, no 10, p. 967-971
Keywords [en]
Phosphonium, arsane, condensation reaction, ligands
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-396154DOI: 10.1080/10426507.2019.1631310ISI: 000473079400001OAI: oai:DiVA.org:uu-396154DiVA, id: diva2:1366691
Available from: 2019-10-30 Created: 2019-10-30 Last updated: 2019-10-30Bibliographically approved

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