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A heavy metal-free CuInS2 quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO2 reduction
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry. KTH Royal Inst Technol, Sch Engn Sci, Dept Appl Phys, Stockholm, Sweden.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.ORCID iD: 0000-0002-2913-514X
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
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2019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 55, p. 7918-7921Article in journal (Refereed) Published
Abstract [en]

Heavy metal-free CuInS2 quantum dots (QDs) were employed as a photosensitizer on a NiO photocathode to drive an immobilized molecular Re catalyst for photoelectrochemical CO2 reduction for the first time. A photocurrent of 25 mu A cm(-2) at -0.87 V vs. NHE was obtained, providing a faradaic efficiency of 32% for CO production.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2019. Vol. 55, no 55, p. 7918-7921
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Physical Chemistry
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URN: urn:nbn:se:uu:diva-390783DOI: 10.1039/c9cc04222aISI: 000474306200003PubMedID: 31215919OAI: oai:DiVA.org:uu-390783DiVA, id: diva2:1343413
Funder
Swedish Energy Agency, 11674-8Göran Gustafsson Foundation for Research in Natural Sciences and MedicineStiftelsen Olle Engkvist ByggmästareAvailable from: 2019-08-16 Created: 2019-08-16 Last updated: 2019-08-16Bibliographically approved

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