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Triarylalkenes from the site-selective reductive cross-coupling of benzophenones and aldehydes
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.ORCID iD: 0000-0002-9450-2532
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.ORCID iD: 0000-0002-1691-729X
2019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 43, p. 6030-6033Article in journal (Refereed) Published
Abstract [en]

PhP(Li)TMS converts benzophenones to phosphaalkenes which upon activation under oxidizing, basic conditions react with aromatic aldehydes under the formation of triarylalkenes. The one-pot reaction omits transition metals, proceeds at room temperature and precludes the formation of any homo-coupling products. Systematic substrate variations reveal reactivity patterns that are useful for the identification of ketone/aldehyde combinations that can be coupled in yields up to 80%.

Place, publisher, year, edition, pages
2019. Vol. 55, no 43, p. 6030-6033
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Physical Chemistry Organic Chemistry
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URN: urn:nbn:se:uu:diva-387587DOI: 10.1039/c9cc02972aISI: 000468832200007PubMedID: 31062780OAI: oai:DiVA.org:uu-387587DiVA, id: diva2:1331331
Available from: 2019-06-26 Created: 2019-06-26 Last updated: 2019-06-26Bibliographically approved

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