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Corrosion of copper in pure O2-free water?
SKB, Swedish Nucl Fuel & Waste Management Co, SE-10124 Stockholm, Sweden.
SKB, Swedish Nucl Fuel & Waste Management Co, SE-10124 Stockholm, Sweden.
SKB, Swedish Nucl Fuel & Waste Management Co, SE-10124 Stockholm, Sweden.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.ORCID iD: 0000-0002-7018-9617
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2018 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 137, p. 1-12Article in journal (Refereed) Published
Abstract [en]

Copper exposed to pure, O-2-free water for several months in glass- and metal-contained, well-controlled systems shows no evidence of corrosion, either through hydrogen evolution or through the occurrence of oxidized copper. The results contradict the interpretation of recent experiments where it has been claimed that copper corrodes in pure, O-2-free water far above the very limited extent predicted by established thermodynamic data. Reasons for the different experimental outcomes are discussed. Experimental and theoretical efforts to identify hitherto unknown, potentially corrosion driving species of the Cu-O-H system and studies of copper/water surface reactions are reviewed as background for the present study.

Place, publisher, year, edition, pages
2018. Vol. 137, p. 1-12
Keywords [en]
Copper, Corrosion, Water, Hydrogen
National Category
Corrosion Engineering
Identifiers
URN: urn:nbn:se:uu:diva-387458DOI: 10.1016/j.corsci.2018.02.008ISI: 000436213400001OAI: oai:DiVA.org:uu-387458DiVA, id: diva2:1330363
Available from: 2019-06-25 Created: 2019-06-25 Last updated: 2019-06-25Bibliographically approved

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