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Copper in ultrapure water, a scientific issue under debate
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
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2017 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 122, p. 53-60Article in journal (Refereed) Published
Abstract [en]

The corrosion properties of copper in ultrapure water have been studied experimentally by submerging copper samples (99.9999%) in pure water for up to 29 months. The surface was first electropolished at ambient temperature, then exposed to hydrogen gas treatment at 300-400 degrees C, thereby reducing the bulk hydrogen content to 0.03 ppm. These copper samples, the water and the glassware were all then subjected to precise chemical analysis. Great care was taken to avoid contamination. After exposure, only similar to 6 mu g/L copper had accumulated in the water phase. Electron spectroscopy could not detect Cu2O or any other oxidation products containing copper.

Place, publisher, year, edition, pages
PERGAMON-ELSEVIER SCIENCE LTD , 2017. Vol. 122, p. 53-60
Keywords [en]
Copper, XPS, AES, Oxidation
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-330714DOI: 10.1016/j.corsci.2017.03.014ISI: 000404490600006OAI: oai:DiVA.org:uu-330714DiVA, id: diva2:1147971
Available from: 2017-10-09 Created: 2017-10-09 Last updated: 2017-12-28Bibliographically approved

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Ottosson, MikaelBoman, MatsBerastegui, PedroAndersson, YvonneHedlund, MariaKorvela, MarcusBerger, Rolf
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