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Catalyst solvent interactions in a dinuclear Ru-based water oxidation catalyst
Stockholm Univ, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden..
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
Stockholm Univ, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden..
Stockholm Univ, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden..
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2016 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 45, no 47, p. 19024-19033Article in journal (Refereed) Published
Abstract [en]

Photocatalytic water oxidation represents a key process in conversion of solar energy into fuels and can be facilitated by the use of molecular transition metal-based catalysts. A novel straightforward approach for covalent linking of the catalytic units to other moieties is demonstrated by preparation of a dinuclear complex containing two [Ru(pdc)(pic)(3)]-derived units (pdc = 2,6-pyridinedicarboxylate, pic = 4-picoline). The activity of this complex towards chemical and photochemical oxidation of water was evaluated and a detailed insight is given into the interactions between the catalyst and acetonitrile, a common co-solvent employed to increase solubility of water oxidation catalysts. The solvent-induced transformations were studied by electrochemical and spectroscopic techniques and the relevant quantitative parameters were extracted.

Place, publisher, year, edition, pages
2016. Vol. 45, no 47, p. 19024-19033
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-313525DOI: 10.1039/c6dt03789eISI: 000390082900029OAI: oai:DiVA.org:uu-313525DiVA, id: diva2:1071007
Funder
Swedish Research Council, 621-2013-4872Knut and Alice Wallenberg FoundationCarl Tryggers foundation Available from: 2017-02-02 Created: 2017-01-20 Last updated: 2017-11-29Bibliographically approved

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