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General, Simple, and Chemoselective Catalysts for the Isomerization of Allylic Alcohols: The Importance of the Halide Ligand
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.
Stockholm University, Faculty of Science, Department of Organic Chemistry.ORCID iD: 0000-0002-1333-7740
Stockholm University, Faculty of Science, Department of Organic Chemistry.
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2016 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 22, no 44, p. 15659-15663Article in journal (Refereed) Published
Abstract [en]

Remarkably simple Ir-III catalysts enable the isomerization of primary and sec-allylic alcohols under very mild reaction conditions. X-ray absorption spectroscopy (XAS) and mass spectrometry (MS) studies indicate that the catalysts, with the general formula [Cp*Ir-III], require a halide ligand for catalytic activity, but no additives or additional ligands are needed.

Place, publisher, year, edition, pages
2016. Vol. 22, no 44, p. 15659-15663
Keyword [en]
allylic alcohols, X-ray absorption spectroscopy, isomerization, iridium, reaction mechanisms
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:su:diva-136049DOI: 10.1002/chem.201603825ISI: 000386795700016PubMedID: 27650170OAI: oai:DiVA.org:su-136049DiVA, id: diva2:1058822
Funder
Knut and Alice Wallenberg FoundationSwedish Research Council
Available from: 2016-12-21 Created: 2016-11-29 Last updated: 2018-03-02Bibliographically approved

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