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Improving Estimates of the Crystallization Driving Force: Investigation into the Dependence on Temperature and Composition of Activity Coefficients in Solution
University of Limerick, Ireland.
University of Limerick, Ireland.ORCID iD: 0000-0002-6647-3308
University of Limerick, Ireland.
2016 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 16, no 12, p. 6951-6960Article in journal (Refereed) Published
Abstract [en]

The influence of temperature and composition on solution activity coefficients has been investigated. Under most conditions, the temperature dependence of the activity coefficient is much weaker than the composition dependence. A novel and more accurate approach to estimate crystallization driving forces is proposed, where, rather than neglecting the activity coefficient ratio, it can be estimated from solid−liquid equilibrium data.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2016. Vol. 16, no 12, p. 6951-6960
Keyword [en]
activity coefficient, thermodynamics, solubility
National Category
Other Chemical Engineering Physical Chemistry
Research subject
Chemical Engineering; Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-198541DOI: 10.1021/acs.cgd.6b01137ISI: 000389624200034Scopus ID: 2-s2.0-85002946014OAI: oai:DiVA.org:kth-198541DiVA, id: diva2:1057385
Note

QC 20161219

Available from: 2016-12-17 Created: 2016-12-17 Last updated: 2018-03-14Bibliographically approved

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fulltext(1972 kB)18 downloads
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Svärd, MichaelRasmuson, Åke C.
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