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Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li0.2Ni0.2Mn0.6]O-2
Univ Oxford, Dept Mat, Parks Rd, Oxford OX1 3PH, England.;Univ Oxford, Dept Chem, Parks Rd, Oxford OX1 3PH, England..
Univ Oxford, Dept Mat, Parks Rd, Oxford OX1 3PH, England.;Univ Oxford, Dept Chem, Parks Rd, Oxford OX1 3PH, England..
Univ Oxford, Dept Mat, Parks Rd, Oxford OX1 3PH, England.;Univ Oxford, Dept Chem, Parks Rd, Oxford OX1 3PH, England..
Univ Oxford, Dept Mat, Parks Rd, Oxford OX1 3PH, England.;Univ Oxford, Dept Chem, Parks Rd, Oxford OX1 3PH, England..
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2016 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 138, no 35, 11211-11218 p.Article in journal (Refereed) Published
Abstract [en]

Conventional intercalation cathodes for lithium batteries store charge in redox reactions associated with the transition metal cations, e.g., Mn3+/4+ in LiMn2O4, and this limits the energy storage of Li-ion batteries. Compounds such as Li[Li0.2Ni0.2Mn0.6]O-2 exhibit a capacity to store charge in excess of the transition metal redox reactions. The additional capacity occurs at and above 4.5 V versus Li+/Li. The capacity at 4.5 V is dominated by oxidation of the O-2(-) anions accounting for similar to 0.43 e(-)/formula unit, with an additional 0.06 e(-)/formula unit being associated with O loss from the lattice. In contrast, the capacity above 4.5 V is mainly O loss, similar to 0.08 e(-)/formula. The O redox reaction involves the formation of localized hole states on O during charge, which are located on O coordinated by (Mn4+/Li+). The results have been obtained by combining operando electrochemical mass spec on 180 labeled Li[Li0.2Ni0.2Mn0.6]O-2 with XANES, soft X-ray spectroscopy, resonant inelastic X-ray spectroscopy, and Raman spectroscopy. Finally the general features of O redox are described with discussion about the role of comparatively ionic (less covalent) 3d metal oxygen interaction on anion redox in lithium rich cathode materials.

Place, publisher, year, edition, pages
2016. Vol. 138, no 35, 11211-11218 p.
National Category
Condensed Matter Physics
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URN: urn:nbn:se:uu:diva-305471DOI: 10.1021/jacs.6b05111ISI: 000382901800031PubMedID: 27498756OAI: oai:DiVA.org:uu-305471DiVA: diva2:1038551
Funder
Swedish Research Council
Available from: 2016-10-19 Created: 2016-10-18 Last updated: 2016-10-19Bibliographically approved

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Massel, FelixDuda, Laurent C.
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