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Water oxidation catalyzed by molecular di- and nonanuclear Fe complexes: importance of a proper ligand framework
Lund University, Sweden.
Stockholm University, Sweden.
Stockholm University, Sweden.
Stockholm University, Sweden.
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2016 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 45, no 34, 13289-13293 p.Article in journal (Refereed) Published
Abstract [en]

The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the di-nucleating ligand 2,2-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the one-electron oxidant [Ru(bpy)(3)](3+).

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2016. Vol. 45, no 34, 13289-13293 p.
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Organic Chemistry
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URN: urn:nbn:se:liu:diva-131882DOI: 10.1039/c6dt01554aISI: 000382144300004PubMedID: 27265239OAI: oai:DiVA.org:liu-131882DiVA: diva2:1034922
Note

Funding Agencies|Knut and Alice Wallenberg Foundation; Swedish Research Council [621-2013-4872]; Carl Trygger Foundation; DFG (Metal Sites in Biomolecules: Structures, Regulation and Mechanisms) [IRTG 1422]; Swedish Energy Agency

Available from: 2016-10-13 Created: 2016-10-11 Last updated: 2016-11-07

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Zeglio, Erica
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