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Biomass- and coke oven gas based methanol production
2007 (English)Independent thesis Advanced level (professional degree), 20 credits / 30 HE creditsStudent thesis
Abstract [en]

This study considers production of methanol as a motor fuel, generated from coke oven gas at the steel mill SSAB Tunnplåt in Luleå. In addition, different systems with a biomass gasification plant included are considered. The produced synthesis gas is mixed with the coke oven gas to enhance the methanol production. Different technologies for production of the alcohol are applied. The selected techniques are based upon their advantageous by economical and technical characteristics. The selected systems are modelled in Aspen plus, which is a widely used process simulation software. The resulting dimensions of streams, units and the energy balances are subsequently used for the economic analysis. Global warming caused by an increased concentration of greenhouse gases is of major concern today. It is predicted that global warming will cause sea level rise and other environmental impacts that may harm humans and nature. The significant increase of greenhouse gases over the last 200 years is almost entirely due to human activities and particularly due to combustion of fossil fuels. By using biomass as fuel for production of methanol as motor fuel, it would contribute to decrease the total green house gas emission level. The coke oven gas which origins from fossil based coal, could be used in a better manner as fuel for methanol production than for increase the present electricity production at LULEKRAFT AB (LUKAB). That is because the methanol production leads to a product with lower specific CO2 emissions due to that the conversion- and total plant efficiency are much higher. The wood-pellets produced from sawdust at Bioenergi are to a large extent exported from the county to heat and power plants, which purchase the pellets to a low price. A better option would be to use the sawdust for methanol production, which would be more profitable and could be used within the county and thereby also minimize the transportation costs and green house gas emissions. The conclusion is that methanol produced from 400 GWh coke oven gas would have a production cost in the range of 1,20-2,44 SEK/litre. Methanol produced from both 420 GWh sawdust and the coke oven gas would result in a production cost in the range of 1,20-2,70 SEK/litre. The minimum methanol sale price was calculated via a fuel value analysis which analyzed the fuel input value within the MEOH plant, LUKAB and Bioenergi. The methanol produced from the coke oven gas would have a minimum sale price in the range of 1,20-2,68 SEK/litre. Methanol produced from both sawdust and coke oven gas would result in a minimum sale price in the range of 1,28-3,17 SEK/litre. The produced methanol from sawdust and coke oven gas could potentially replace about half of the present gasoline demand in the county. This would decrease the import of fossil based motor fuel considerable.

Place, publisher, year, edition, pages
Keyword [en]
Technology, Renewable energy, Methanol, Metanol, Motor fuel, Transportation fuel, Motorbränsle, coke oven gas, biomass
Keyword [sv]
URN: urn:nbn:se:ltu:diva-53133ISRN: LTU-EX--07/189--SELocal ID: a3283feb-ee11-475c-bc39-4ad6f4bae7c0OAI: diva2:1026507
Subject / course
Student thesis, at least 30 credits
Educational program
Mechanical Engineering, master's level
Validerat; 20101217 (root)Available from: 2016-10-04 Created: 2016-10-04Bibliographically approved

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