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Consequences of conformational flexibility in hydrogen-bond-driven self-assembly processes
Eindhoven University of Technology, Netherlands.
Linköping University, Department of Physics, Chemistry and Biology, Theoretical Chemistry. Linköping University, Faculty of Science & Engineering. University of Limoges, France.
Eindhoven University of Technology, Netherlands.
Eindhoven University of Technology, Netherlands.
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2016 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 52, no 72, 10870-10873 p.Article in journal (Refereed) Published
Abstract [en]

We report the synthesis and self-assembly of chiral, conformationally flexible C-3-symmetrical trisamides. A strong Cotton effect is observed for the supramolecular polymers in linear alkanes but not in cyclic alkanes. MD simulations suggest 2:1 conformations of the amides within the aggregates in both types of solvents, but a chiral bias in only linear alkanes.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2016. Vol. 52, no 72, 10870-10873 p.
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Physical Chemistry
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URN: urn:nbn:se:liu:diva-131722DOI: 10.1039/c6cc05593aISI: 000382673600012PubMedID: 27525556OAI: oai:DiVA.org:liu-131722DiVA: diva2:1010219
Note

Funding Agencies|Gravity program [024.001.035]; NWO TOP-PUNT [718.014.003]; Swedish e-Research Center (SeRC); Swedish Research Council [621-2014-4646]

Available from: 2016-10-03 Created: 2016-09-30 Last updated: 2016-11-02

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