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Allylic alcohols as synthetic enolate equivalents: Isomerisation and tandem reactions catalysed by transition metal complexes
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.
Stockholms universitet, Naturvetenskapliga fakulteten, Institutionen för organisk kemi.ORCID-id: 0000-0002-7898-317X
2012 (engelsk)Inngår i: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 41, nr 6, s. 1660-1670Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Allylic alcohols can be isomerised into carbonyl compounds by transition metal complexes. In the last few years, catalyst design and development have resulted in highly efficient isomerisations under mild reaction conditions, including enantioselective versions. In addition, the isomerisation of allylic alcohols has been combined with C-C bond forming reactions when electrophiles such as aldehydes or imines were present in the reaction mixture. Also, C-F bonds can be formed when electrophilic fluorinating reagents are used. Thus, allylic alcohols can be treated as latent enol(ate)s. In this article, we highlight the latest developments concerning the isomerisation of allylic alcohols into carbonyl compounds, focusing in particular on tandem isomerisation/C-C or C-heteroatom bond formation processes. Significant attention is given to the mechanistic aspects of the reactions.

sted, utgiver, år, opplag, sider
2012. Vol. 41, nr 6, s. 1660-1670
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URN: urn:nbn:se:su:diva-76742DOI: 10.1039/c1dt11678aISI: 000299292400002OAI: oai:DiVA.org:su-76742DiVA, id: diva2:527209
Forskningsfinansiär
Swedish Research CouncilKnut and Alice Wallenberg FoundationVINNOVAKnut and Alice Wallenberg FoundationBerzelii Centre EXSELENT
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Tilgjengelig fra: 2012-05-18 Laget: 2012-05-16 Sist oppdatert: 2017-11-10bibliografisk kontrollert

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