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A general approach to the covalent immobilization of single polymers
Portland State University.ORCID-id: 0000-0003-1121-4007
2006 (engelsk)Inngår i: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 45, nr 37, s. 6207-6210Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Stuck fast: The covalent immobilization of polymeric single molecules is achieved by the photochemically induced C-H/N-H insertion reaction of perfluorophenylazides (see picture). When the concentration of the surface azido groups is decreased, isolated polymeric single molecules are observed. This technique is especially suited for materials that do not possess functional groups and are difficult to be immobilized by other means. (Chemical Equation Presented).

sted, utgiver, år, opplag, sider
2006. Vol. 45, nr 37, s. 6207-6210
Emneord [en]
immobilization, photochemistry, polymers, scanning probe microscopy, single-molecule studies
HSV kategori
Identifikatorer
URN: urn:nbn:se:kth:diva-77365DOI: 10.1002/anie.200602097ISI: 000240815100031PubMedID: 16906617OAI: oai:DiVA.org:kth-77365DiVA, id: diva2:492027
Merknad
QC 20120228Tilgjengelig fra: 2012-02-07 Laget: 2012-02-06 Sist oppdatert: 2017-12-08bibliografisk kontrollert

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