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Colorimetric Protein Sensing by Controlled Assembly of Gold Nanoparticles Functionalized with Synthetic Receptors
Uppsala universitet, Teknisk-naturvetenskapliga vetenskapsområdet, Kemiska sektionen, Institutionen för biokemi och organisk kemi.
Vise andre og tillknytning
2009 (engelsk)Inngår i: Small, ISSN 1613-6810, Vol. 5, nr 21, s. 2445-2452Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

A novel strategy is described for the colorimetric sensing of proteins, based on polypeptide-functionalized gold nanoparticles. Recognition is accomplished using a polypeptide sensor scaffold designed to specifically bind to the model analyte, human carbonic anhydrase II (HCAII). The extent of particle aggregation, induced by the Zn2+-triggered dimerization and folding of a second polypeptide also present on the surface of the gold nanoparticle, gives a readily detectable colorimetric shift that is dependent on the concentration of the target protein. In the absence of HCAII, particle aggregation results in a major redshift of the plasmon peak, whereas analyte binding prevented the formation of dense aggregates, significantly reducing the magnitude of the redshift. The versatility of the technique is demonstrated using a second model system based on the recognition of a peptide sequence from the tobacco mosaic virus coat protein (TMVP) by a recombinant antibody fragment (Fab57P). Concentrations down to approximate to 10 nM and approximate to 25 nM are detected for HCAII and Fab57P, respectively. This strategy is proposed as a generic platform for robust and specific protein analysis that can be further developed to monitor a wide range of target proteins.

sted, utgiver, år, opplag, sider
2009. Vol. 5, nr 21, s. 2445-2452
Emneord [en]
bioassays, gold, helical structures, hybrid materials, nanoparticles
HSV kategori
Identifikatorer
URN: urn:nbn:se:uu:diva-127413DOI: 10.1002/smll.200900530ISI: 000271791100015OAI: oai:DiVA.org:uu-127413DiVA, id: diva2:329858
Tilgjengelig fra: 2010-07-14 Laget: 2010-07-13 Sist oppdatert: 2022-01-28bibliografisk kontrollert

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