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Importance of the micro-lattice structure of selective laser melting processed Mo/Mo(x)S(x+1) composite: Corrosion studies on the electrochemical performance in aqueous solutions
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science. Tallinn Univ Technol, Dept Mech & Ind Engn, Ehitajate Tee 5, EE-19086 Tallinn, Estonia..ORCID iD: 0000-0003-2316-7869
Inst Adv Studies Basic Sci, Dept Chem, Zanjan 4513766731, Iran..
Tallinn Univ Technol, Dept Mat & Environm Technol, Ehitajate Tee 5, EE-19086 Tallinn, Estonia..
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2022 (English)In: Materials Today Chemistry, E-ISSN 2468-5194, Vol. 26, article id 101219Article in journal (Refereed) Published
Abstract [en]

Selective laser melting (SLM) based processing of Mo-based samples is challenging due to solidification cracking. We here demonstrate that the addition of 2 wt% MoS2 to the Mo feedstock markedly improves crack mitigation of SLM-processed Mo/MoS2/Mo2S3 composite micro-lattice structures (SLM-Mo/ Mo(x)S(x+1)). Crack inhibition is suggested to be a result of Mo2S3 formation, decreased lattice strain (0.04 4%), and a decrease in accumulated residual stresses. The increased values of polarization resistance from 42.3 and 19.2 kU cm2 to 437 and 78.2 kU cm2, respectively verified the hindering effect of the composition on stress corrosion cracking (SCC) and surface oxidation cracking. However, an increased corrosion current density, from 1.22 to 10.2 mA/cm2, and cathodic Tafel constant, from 175 to 260.5 mV, confirmed the decreased polarization resistance and occurrence of different types of corrosion such as SCC and pitting. The strategy to add 2 wt% MoS2 to the Mo feedstock enables the fabrication of hightemperature micro-lattice structure components with improved corrosion resistance properties applicable in e.g., electronic, power semiconductor heat sinks, offshore-, aerospace-, defense-, or particularly novel sodium-ion energy storage applications.

Place, publisher, year, edition, pages
Elsevier BV , 2022. Vol. 26, article id 101219
Keywords [en]
Additive manufacturing, SLM, Molybdenum, MoS2, Novel composite, Corrosion resistivity, Sustainable 3D printing
National Category
Corrosion Engineering Composite Science and Engineering
Identifiers
URN: urn:nbn:se:kth:diva-322855DOI: 10.1016/j.mtchem.2022.101219ISI: 000877684800006Scopus ID: 2-s2.0-85140319422OAI: oai:DiVA.org:kth-322855DiVA, id: diva2:1724666
Note

QC 20230109

Available from: 2023-01-09 Created: 2023-01-09 Last updated: 2024-02-12Bibliographically approved

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