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Fast-charging effects on ageing for energy-optimized automotive LiNi1/3Mn1/3Co1/3O2/graphite prismatic lithium-ion cells
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Kemiteknik, Tillämpad elektrokemi.ORCID-id: 0000-0003-3436-6134
Uppsala Univ, Angstrom Lab, Dept Chem, Box 538, SE-75121 Uppsala, Sweden..
Uppsala Univ, Angstrom Lab, Dept Chem, Box 538, SE-75121 Uppsala, Sweden.;Scania CV AB, SE-15187 Sodertalje, Sweden..
KTH, Skolan för kemi, bioteknologi och hälsa (CBH), Kemiteknik, Tillämpad elektrokemi. Scania CV AB, SE-15187 Sodertalje, Sweden.ORCID-id: 0000-0003-4901-5820
Vise andre og tillknytning
2019 (engelsk)Inngår i: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 422, s. 175-184Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The reactions in energy-optimized 25 Ah prismatic NMC/graphite lithium-ion cell, as a function of fast charging (1C-4C), are more complex than earlier described. There are no clear charging rate dependent trends but rather different mechanisms dominating at the different charging rates. Ageing processes are faster at 3 and 4C charging. Cycling with 3C-charging results in accelerated lithium plating but the 4C-charging results in extensive gas evolution that contribute significantly to the large cell impedance rise. Graphite exfoliation and accelerated lithium inventory loss point to the graphite electrode as the source of the gas evolution. The results are based on careful post-mortem analyses of electrodes using: scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and electrochemical impedance spectroscopy (EIS). SEM results show particle cracking independent of the charging rate used for the cycling. XPS and EIS generally indicate thicker surface film and larger impedance, respectively, towards the edge of the jellyrolls. For the intended application of a battery electric inner-city bus using this type of cell, charging rates of 3C and above are not feasible, considering battery lifetime. However, charging rates of 2C and below are too slow from the point of view of practical charging time.

sted, utgiver, år, opplag, sider
ELSEVIER SCIENCE BV , 2019. Vol. 422, s. 175-184
Emneord [en]
Fast charging, Lithium-ion battery, Ageing, Energy battery, Electric vehicle
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Identifikatorer
URN: urn:nbn:se:kth:diva-252373DOI: 10.1016/j.jpowsour.2019.02.095ISI: 000465365900021Scopus ID: 2-s2.0-85063095386OAI: oai:DiVA.org:kth-252373DiVA, id: diva2:1322142
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QC 20190610

Tilgjengelig fra: 2019-06-10 Laget: 2019-06-10 Sist oppdatert: 2019-06-10bibliografisk kontrollert

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Mussa, AbdilbariKlett, MatildaLindbergh, GöranLindström, Rakel WrelandSvens, Pontus
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